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SciMater™ Research-Grade Ternary MAX Phase Powder (312 Series)

  • Product Code:Ti3AlCN, Cr2VAlC2, Ti3TaAlC2, TiNbAlC2, Ti4VAlC2, Th2V1.5AlC2, TiV2AlC2
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SciMater™ ADVANCED LAYERED MATERIALS

Ternary MAX Phase (312) Research-Grade Powders

Multi-Element Layered Ceramic Materials | Nominal Purity ≥99% | 200–500 Mesh Options | Standard Packaging: 1 g, 5 g, and 50 g

MAX Phase (312) Research-Grade Powder Purity ≥99% 9 Product Configurations Multi-Element M-Site Systems

This series includes Ti₃AlCN, Cr₂VAlC₂, Ti₃TaAlC₂, TiNbAlC₂, Ti₄VAlC₂, Th₂V₁.₅AlC₂, TiV₂AlC₂, and two Ti₃AlC₂ configurations. These materials are suitable for research on MAX-phase structures, elemental site occupancy, interlayer bonding, sintering, coatings, composites, and functional properties.

Product Series MAX Phase (312)
Nominal Purity ≥99%
Available Mesh Sizes 200–500 Mesh
Standard Packaging 1 g / 5 g / 50 g

Product Description

Ternary MAX phases of the 312 type are commonly represented by the general formula M₃AX₂, where M is a transition metal, A is a main-group element, and X is C, N, or a mixed C/N system. Their structures consist of alternating M–X and A layers, making them suitable for studying how elemental composition, stoichiometry, site occupancy, and interlayer interactions influence material structure and performance.

This series includes conventional Ti₃AlC₂, carbonitrides, multi-metal M-site materials, and special-composition products. Some catalog models do not follow an exact integer M₃AX₂ stoichiometry. Their actual structures, primary-phase content, elemental occupancy, and secondary-phase composition should be confirmed using batch-specific XRD, elemental analysis, and microscopic characterization.

Series Specifications

ParameterProduct Information
Product SeriesTernary MAX Phase (312) Research-Grade Powders
General Structural FormulaM₃AX₂; special-stoichiometry products should be identified by their specific model
Product TypesCarbides, carbonitrides, multi-metal M-site materials, and special-composition layered materials
Product FormPowder
Product GradeResearch Grade
Nominal Purity≥99%
Available Mesh Sizes200, 300, 400, and 500 mesh, depending on the product model
Standard Packaging1 g, 5 g, and 50 g
Primary ElementsTi, Cr, V, Ta, Nb, Th, Al, C, N, and related elements
Characterization DataBatch-specific XRD, SEM, EDS, and particle-size data may be available upon request
Customization ServicesSpecial particle sizes, packaging, bulk quantities, and characterization requirements are available upon request
Inventory StatusPlease Inquire

Core Information Comparison Across the Full Product Series

Product ModelProduct ConfigurationComposition TypeM-Site ElementsA-Site ElementX-Site ElementsStoichiometric FeatureRecommended Research Areas
Ti₃AlCNStandard Research GradeTitanium Aluminum CarbonitrideTiAlC and NMixed C/N X-SiteCarbonitride structures, C/N site occupancy, thermal and mechanical properties, and functional-performance studies
Cr₂VAlC₂Standard Research GradeCr/V Multi-Metal M-Site CarbideCr and VAlCCr₂V Multi-Metal M-SiteM-site ordering, elemental occupancy, crystal structure, and interfacial-property studies
Ti₃TaAlC₂Standard Research GradeTi/Ta Multi-Metal M-Site CarbideTi and TaAlCSpecial Ti/Ta RatioHeavy-element incorporation, lattice variation, elemental occupancy, and thermal and mechanical studies
TiNbAlC₂Standard Research GradeTi/Nb Multi-Metal M-Site CarbideTi and NbAlCSpecial Ti/Nb RatioElement substitution, solid-solution behavior, crystal structure, electronic properties, and interface studies
Ti₄VAlC₂Standard Research GradeTi/V Multi-Metal M-Site CarbideTi and VAlCSpecial Ti/V RatioMulti-metal composition, structural stability, solid-solution behavior, and functional-performance studies
Th₂V₁.₅AlC₂Special-Composition Research GradeTh/V Multi-Metal M-Site CarbideTh and VAlCNon-Integer M-Site RatioNon-integer composition, complex site occupancy, structural stability, and special layered-material studies
TiV₂AlC₂Standard Research GradeTi/V Multi-Metal M-Site CarbideTi and VAlCTiV₂ Multi-Metal M-SiteM-site ordering, elemental occupancy, electrochemical behavior, structure, and interface studies
Ti₃AlC₂High-Purity TypeTitanium Aluminum CarbideTiAlCConventional Ti₃AlC₂ ConfigurationFundamental MAX-phase research, sintering, coatings, composites, and property characterization
Ti₃AlC₂Aluminum-Rich TypeTitanium Aluminum CarbideTiAlCExcess-Al ConfigurationEffects of aluminum content, sintering compensation, phase formation, and process-condition studies
The information above is organized according to catalog descriptions and listed chemical formulas. For complex M-site systems, non-integer compositions, and special-stoichiometry products, actual structure, elemental occupancy, phase ratios, and secondary-phase composition should be confirmed using batch-specific characterization data.

Key Features

Product FeatureDescription
Broad Product PortfolioIncludes conventional Ti₃AlC₂, carbonitrides, multi-metal M-site systems, and special-composition products
Diverse Elemental CombinationsIncludes M-site elements such as Ti, Cr, V, Ta, Nb, and Th together with Al, C, and N systems
Suitable for Site-Occupancy StudiesSuitable for research on M-site ordering, elemental substitution, solid solutions, and stoichiometric effects
Research-Grade PowderSuitable for phase characterization, sintering, composite preparation, coatings, and functional-property experiments
Multiple Mesh OptionsAvailable from 200 to 500 mesh to support solid-state reactions, sintering, and fine-dispersion applications
Flexible PackagingStandard packaging of 1 g, 5 g, and 50 g supports screening, preliminary trials, and continuous R&D
Convenient Configuration ComparisonTi₃AlC₂ is available in high-purity and aluminum-rich configurations for different formulation and process studies
Batch Characterization AvailableBatch-specific XRD, SEM, EDS, and particle-size data may be available upon request

Typical Applications

Application AreaApplication Description
Fundamental MAX-Phase ResearchAnalysis of crystal structure, phase composition, lattice parameters, defects, and interlayer interactions
M-Site Ordering ResearchStudy of elemental occupancy, ordering patterns, and structural stability among different transition metals
Element Substitution and Solid SolutionsAnalysis of how substitution by Ti, Cr, V, Ta, Nb, and related elements affects structure and performance
Carbonitride ResearchUse of Ti₃AlCN to study mixed C/N X-sites and the effect of composition on material properties
Powder SinteringResearch on pellet pressing, pressureless sintering, hot pressing, and spark-plasma sintering
High-Temperature PerformanceAnalysis of thermal stability, oxidation behavior, thermal expansion, and high-temperature mechanical properties
Functional CoatingsDevelopment of oxidation-resistant, wear-resistant, conductive, and multifunctional coating formulations
Composite MaterialsCombination with metals, ceramics, polymers, or carbon materials to study interfaces and reinforcement effects
Electrical and Electrochemical ResearchResearch on electrical conduction, electronic structure, electrochemical response, and related functional properties
Layered Derivative MaterialsResearch on A-layer reactions, structural evolution, and new two-dimensional or layered derivative materials

Mesh Size and Packaging Selection

SpecificationKey CharacteristicsRecommended Uses
200 MeshRelatively coarse particles with good flowabilitySolid-state reactions, pellet pressing, sintering, and routine composite preparation
300 MeshBalances flowability and contact areaFormulation screening, powder mixing, and routine material experiments
400 MeshFiner powder with a relatively larger contact areaSlurries, coatings, dispersion, interfacial reactions, and fine mixing
500 MeshSuitable for finer-powder applicationsThin-layer coating, fine dispersion, and experiments requiring higher fineness
1 g PackageSmall quantity suitable for screening multiple modelsPreliminary characterization, material screening, formulation validation, and small-scale trials
5 g PackageSuitable for routine trials and process screeningSintering-condition studies, composite formulations, coatings, and performance testing
50 g PackageSuitable for continuous experiments and staged R&DBatch mixing, sintering, coatings, and multi-group comparative experiments
Mesh size is a sieving specification and does not represent the complete particle-size distribution. When specific D10, D50, or D90 values are required, please review the particle-size data for the relevant batch.

Instructions for Use

ProcedureInstructions
Model SelectionSelect the product according to the target elemental system, M-site ratio, X-site type, particle size, and research objective
Batch VerificationBefore using complex-composition or special models, verify the chemical formula, XRD data, and elemental-analysis results
Opening and SamplingUse clean, dry tools for sampling and avoid contamination from moisture, oils, or other powders
Powder DryingFor moisture-sensitive experiments, low-temperature vacuum drying or inert-atmosphere drying may be used
DispersionSelect a compatible solvent and improve dispersion through stirring, ultrasonication, or low-energy ball milling
Material MixingMix uniformly with metals, ceramics, polymers, or other functional materials according to the experimental formulation
Pellet FormingPellet pressing may be performed before sintering; forming pressure should be adjusted according to particle size, binder, and equipment conditions
Heat TreatmentTemperature, atmosphere, heating rate, and holding time should be optimized through preliminary trials according to product composition
Coating PreparationThe powder may be formulated into a slurry and applied by doctor blading, spraying, or another suitable film-forming method according to substrate and target thickness
Material CharacterizationXRD, SEM, TEM, EDS, XPS, and particle-size analysis are recommended to verify material condition

Product Selection Guide

Experimental RequirementRecommended Product
Conventional 312-Type MAX-Phase ResearchTi₃AlC₂ High-Purity Type
Aluminum Content and Sintering-Compensation StudiesTi₃AlC₂ Aluminum-Rich Type
Mixed C/N X-Site ResearchTi₃AlCN
Cr/V Multi-Metal M-Site ResearchCr₂VAlC₂
Ti/V Multi-Metal M-Site ResearchTiV₂AlC₂ or Ti₄VAlC₂
Ti/Nb Element-Substitution ResearchTiNbAlC₂
Ti/Ta Multi-Metal M-Site ResearchTi₃TaAlC₂
Non-Integer M-Site Composition ResearchTh₂V₁.₅AlC₂; safety and regulatory conditions must be confirmed before use
Preliminary Material ScreeningPrioritize 1 g packages and 200- or 400-mesh specifications
Continuous Sintering or Composite ExperimentsPrioritize 5 g or 50 g packages

Recommended Characterization

Characterization MethodPrimary Purpose
XRDConfirm the primary MAX phase, crystal structure, lattice parameters, and possible secondary phases
SEMObserve particle morphology, surface condition, layered features, and agglomeration
TEM / STEMObserve layered structures, local lattice, elemental occupancy, and interfacial structures
EDSAnalyze elemental composition, ratios, and spatial distribution
XPSAnalyze surface chemical states and bonding information
Particle-Size AnalysisDetermine particle-size distribution parameters such as D10, D50, and D90
Thermal AnalysisStudy thermal stability, oxidation processes, mass changes, and thermal behavior
Electrical TestingStudy electrical resistivity, conduction behavior, and temperature-dependent transport properties
Mechanical TestingStudy hardness, elasticity, indentation, fracture, and damage behavior
Quantitative Elemental AnalysisVerify actual elemental ratios in multi-metal M-site, non-integer-composition, and aluminum-rich products

Storage and Safety

ItemRecommendation
Storage EnvironmentStore sealed in a cool, dry place away from direct light
Storage After OpeningReseal promptly after use and avoid prolonged exposure to air and moisture
Long-Term StorageVacuum or inert-gas protection may be used when required
Personal ProtectionWear laboratory gloves, a dust mask or suitable respirator, protective clothing, and safety goggles
Dust ControlAvoid generating airborne dust and operate in a fume hood or an area with local dust extraction
Cross-ContaminationUse dedicated or thoroughly cleaned sampling, grinding, and mixing tools for different product models
Waste DisposalDispose of the material according to laboratory requirements for inorganic powders, heavy metals, or special-material waste
Intended UseFor scientific research and industrial R&D only; not intended for food, medical, or human-use applications
Th₂V₁.₅AlC₂ contains thorium. Procurement, transportation, storage, handling, and disposal should be performed only by institutions with the required safety systems, management procedures, and regulatory authorization. A formal risk assessment should be completed before use, and the laboratory must confirm that appropriate protective measures are in place.

Frequently Asked Questions

1. What is a 312-type MAX phase?
A conventional 312-type MAX phase is commonly represented by M₃AX₂, where M is a transition metal, A is a main-group element, and X is C or N. This series also includes multi-metal M-site systems, mixed C/N compositions, and special-stoichiometry products. Their actual structures should be evaluated using batch-specific characterization results.
2. Do all models in this series strictly follow M₃AX₂ stoichiometry?
Not necessarily. Some products contain multi-metal M-sites, non-integer ratios, or special stoichiometries and are classified according to the supply catalog. When strict requirements apply to structural type, elemental occupancy, or primary-phase content, batch-specific XRD, elemental analysis, and microscopic characterization should be reviewed.
3. What is the difference between high-purity and aluminum-rich Ti₃AlC₂?
The high-purity type is based on a conventional Ti₃AlC₂ configuration. The aluminum-rich type uses a higher Al content and is suitable for studying aluminum-volatilization compensation, phase formation, and sintering processes. Actual elemental ratios and phase composition should be confirmed using batch-specific data.
4. How should I choose among 200, 300, 400, and 500 mesh?
The 200-mesh grade is suitable for solid-state reactions, pellet pressing, and sintering. The 300-mesh grade is suitable for routine mixing and formulation screening. The 400-mesh grade is suitable for slurries, coatings, and dispersion. The 500-mesh grade is suitable for fine dispersion and experiments requiring higher powder fineness. Mesh size does not represent the complete particle-size distribution.
5. Does nominal purity ≥99% mean that the primary MAX phase content is also ≥99%?
Not necessarily. Chemical purity and phase purity are different specifications. When strict requirements apply to the primary MAX-phase ratio, secondary phases, multi-metal site occupancy, or actual stoichiometry, batch-specific XRD, elemental-analysis, and particle-size data should be reviewed.

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Ternary MAX Phase (312) Specifications / Price List

Research-Grade Powder ' Purity ≥99% ' 200–500 Mesh Available ' 1 g, 5 g, and 50 g Options

Product ModelMesh Size1 g5 g50 g
Ti₃AlCN200 Mesh$7$30$255
300 Mesh$7$33$281
400 Mesh$8$36$306
500 Mesh$9$39$332
Cr₂VAlC₂200 Mesh$40$180$1,530
300 Mesh$41$183$1,556
400 Mesh$41$186$1,581
500 Mesh$42$189$1,607
Ti₃TaAlC₂200 Mesh$40$180$1,530
300 Mesh$41$183$1,556
400 Mesh$41$186$1,581
500 Mesh$42$189$1,607
TiNbAlC₂200 Mesh$40$180$1,530
300 Mesh$41$183$1,556
400 Mesh$41$186$1,581
500 Mesh$42$189$1,607
Ti₄VAlC₂200 Mesh$40$180$1,530
300 Mesh$41$183$1,556
400 Mesh$41$186$1,581
500 Mesh$42$189$1,607
Th₂V₁.₅AlC₂200 Mesh$50$225$1,913
300 Mesh$51$228$1,938
400 Mesh$51$231$1,964
500 Mesh$52$234$1,989
TiV₂AlC₂200 Mesh$50$225$1,913
300 Mesh$51$228$1,938
400 Mesh$51$231$1,964
500 Mesh$52$234$1,989
Ti₃AlC₂200 Mesh$31$139$833
400 Mesh$33$149$889
Ti₃AlC₂ — Excess Aluminum200 Mesh$30$133$560
400 Mesh$31$140$583

Partial references citing our materials (from Google Scholar)


Carbon Dioxide Reduction

1. ACS Nano Strain Relaxation in Metal Alloy Catalysts Steers the Product Selectivity of Electrocatalytic CO2 Reduction

The bipolar membrane (Fumasep FBM) in this paper was purchased from SCI Materials Hub, which was used in rechargeable Zn-CO2 battery tests. The authors reported a strain relaxation strategy to determine lattice strains in bimetal MNi alloys (M = Pd, Ag, and Au) and realized an outstanding CO2-to-CO Faradaic efficiency of 96.6% with outstanding activity and durability toward a Zn-CO2 battery.


2. Front. Chem. Boosting Electrochemical Carbon Dioxide Reduction on Atomically Dispersed Nickel Catalyst

In this paper, Vulcan XC-72R was purchased from SCI Materials Hub. Vulcan XC 72R carbon is the most common catalyst support used in the anode and cathode electrodes of Polymer Electrolyte Membrane Fuel Cells (PEMFC), Direct Methanol Fuel Cells (DMFC), Alkaline Fuel Cells (AFC), Microbial Fuel Cells (MFC), Phosphoric Acid Fuel Cells (PAFC), and many more!


3. Adv. Mater. Partially Nitrided Ni Nanoclusters Achieve Energy-Efficient Electrocatalytic CO2 Reduction to CO at Ultralow Overpotential

An AEM membrane (Sustainion X37-50 Grade RT, purchased from SCI Materials Hub) was activated in 1 M KOH for 24 h, washed with ultra-purity water prior to use.


4. Adv. Funct. Mater. Nanoconfined Molecular Catalysts in Integrated Gas Diffusion Electrodes for High-Current-Density CO2 Electroreduction

In this paper (Supporting Information), an anion exchanged membrane (Fumasep FAB-PK-130 obtained from SCI Materials Hub (www.scimaterials.cn)) was used to separate the catholyte and anolyte chambers.

SCI Materials Hub: we also recommend our Fumasep FAB-PK-75 for the use in a flow cell.


5. Appl. Catal. B Efficient utilization of nickel single atoms for CO2 electroreduction by constructing 3D interconnected nitrogen-doped carbon tube network

In this paper, the Nafion 117 membrane was obtained from SCI Materials Hub.


6. Vacuum Modulable Cu(0)/Cu(I)/Cu(II) sites of Cu/C catalysts derived from MOF for highly selective CO2 electroreduction to hydrocarbons

In this paper, Proton exchange membrane (Nafion 117), Nafion D520, and Toray 060 carbon paper were purchased from SCI Materials Hub.


7. National Science Review Confinement of ionomer for electrocatalytic CO2 reduction reaction via efficient mass transfer pathways

An anion exchange membrane (PiperION-A15-HCO3) was obtained from SCI Materials Hub.


8. Catalysis Communications Facilitating CO2 electroreduction to C2H4 through facile regulating {100} & {111} grain boundary of Cu2O

Carbon paper (TGPH060), membrane solution (Nafion D520), and ionic membrane (Nafion N117) were obtained from Wuhu Eryi Material Technology Co., Ltd (a company under SCI Materials Hub).


Batteries

1. J. Mater. Chem. A Blocking polysulfides with a Janus Fe3C/N-CNF@RGO electrode via physiochemical confinement and catalytic conversion for high-performance lithium–sulfur batteries

Graphene oxide (GO) in this paper was obtained from SCI Materials Hub. The authors introduced a Janus Fe3C/N-CNF@RGO electrode consisting of 1D Fe3C decorated N-doped carbon nanofibers (Fe3C/N-CNFs) side and 2D reduced graphene oxide (RGO) side as the free-standing carrier of Li2S6 catholyte to improve the overall electrochemical performance of Li-S batteries.


2. Joule A high-voltage and stable zinc-air battery enabled by dual-hydrophobic-induced proton shuttle shielding

This paper used more than 10 kinds of materials from SCI Materials Hub and the authors gave detailed properity comparsion.

The commercial IEMs of Fumasep FAB-PK-130 and Nafion N117 were obtained from SCI Materials Hub.

Gas diffusion layers of GDL340 (CeTech) and SGL39BC (Sigracet) and Nafion dispersion (Nafion D520) were obtained from SCI Materials Hub.

Zn foil (100 mm thickness) and Zn powder were obtained from the SCI Materials Hub.

Commercial 20% Pt/C, 40% Pt/C and IrO2 catalysts were also obtained from SCI Materials Hub.


3. Journal of Energy Chemistry Vanadium oxide nanospheres encapsulated in N-doped carbon nanofibers with morphology and defect dual-engineering toward advanced aqueous zinc-ion batteries

In this paper, carbon cloth (W0S1011) was obtained from SCI Materials Hub. The flexible carbon cloth matrix guaranteed the stabilization of the electrode and improved the conductivity of the cathode.


4. Energy Storage Materials Defect-abundant commercializable 3D carbon papers for fabricating composite Li anode with high loading and long life

The 3D carbon paper (TGPH060 raw paper) were purchased from SCI Materials Hub.


5. Nanomaterials A Stable Rechargeable Aqueous Zn–Air Battery Enabled by Heterogeneous MoS2 Cathode Catalysts

Nafion D520 (5 wt%), and carbon paper (GDL340) were received from SCI-Materials-Hub.


6. SSRN An Axially Directed Cobalt-Phthalocyanine Covalent Organic Polymer as High-Efficient Bifunctional Catalyst for Zn-Air Battery

Carbon cloth (W0S1011) and other electrochemical consumables required for air cathode were provided by SCI Materials Hub.


Oxygen Reduction Reaction

1. J. Chem. Eng. Superior Efficiency Hydrogen Peroxide Production in Acidic Media through Epoxy Group Adjacent to Co-O/C Active Centers on Carbon Black

In this paper, Vulcan XC 72 carbon black, ion membrane (Nafion N115, 127 μL), Nafion solution (D520, 5 wt%), and carbon paper (AvCarb GDS 2230 and Spectracarb 2050A-1050) were purchased from SCI Materials Hub.


2. Journal of Colloid and Interface Science Gaining insight into the impact of electronic property and interface electrostatic field on ORR kinetics in alloy engineering via theoretical prognostication and experimental validation

The 20 wt% Pt3M (M = Cr, Co, Cu, Pd, Sn, and Ir) were purchased from SCI Materials Hub. This work places emphasis on the kinetics of the ORR concerning Pt3M (M = Cr, Co, Cu, Pd, Sn, and Ir) catalysts, and integrates theoretical prognostication and experimental validation to illuminate the fundamental principles of alloy engineering.


Water Electrolysis

1. International Journal of Hydrogen Energy Gold as an efficient hydrogen isotope separation catalyst in proton exchange membrane water electrolysis

The cathodic catalysts of Pt/C (20 wt%, 2–3 nm) and Au/C (20 wt%, 4–5 nm) were purchased from SCI Materials Hub.


2. Small Science Silver Compositing Boosts Water Electrolysis Activity and Durability of RuO2 in a Proton-Exchange-Membrane Water Electrolyzer

Two fiber felts (0.35 mm thickness, SCI Materials Hub) were used as the porous transport layers at both the cathode and the anode.


3. Advanced Functional Materials Hierarchical Crystalline/Amorphous Heterostructure MoNi/NiMoOx for Electrochemical Hydrogen Evolution with Industry-Level Activity and Stability

Anion-exchange membrane (FAA-3-PK-130) was obtained from SCI Materials Hub website.


Fuel Cells

1. Polymer Sub-two-micron ultrathin proton exchange membrane with reinforced mechanical strength

Gas diffusion electrode (60% Pt/C, Carbon paper) was purchased from SCI Materials Hub.


Characterization

1. Chemical Engineering Journal Electrochemical reconstitution of Prussian blue analogue for coupling furfural electro-oxidation with photo-assisted hydrogen evolution reaction

An Au nanoparticle film was deposited on the total reflecting plane of a single reflection ATR crystal (SCI Materials Hub, Wuhu, China) via sputter coater.

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