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SciMater™ Research-Grade Quaternary MAX Phase Powder (211 Series)

  • Product Code:VCrAlC, VTiAlC, TiTinAlC, TiVAlC, TiTaAlC, TiNbAlC, VNbAlC, VTaAlC, VMnAlC
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  • Brand:SciMater™
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  • Keywords:SciMater™ Research-Grade Quaternary MAX Phase Powder (211 Series), SCI Materials Hub
SciMater™ QUATERNARY MAX PHASE MATERIALS

Quaternary MAX Phase (211) Research-Grade Powders

Multi-Metal M-Site Layered Carbides | Nominal Purity ≥99% | 200–500 Mesh Options | Standard Packaging: 1 g, 5 g, and 50 g

Quaternary MAX Phase (211) Research-Grade Powder Purity ≥99% 9 Product Models Multi-Metal M-Site Systems

This series includes VCrAlC, VTiAlC, TiTinAlC, TiVAlC, TiTaAlC, TiNbAlC, VNbAlC, VTaAlC, and VMnAlC. These materials are suitable for studies of multi-metal M-site occupancy, lattice regulation, elemental synergy, powder sintering, composite materials, functional coatings, and layered derivative materials.

Product Series Quaternary MAX (211)
Nominal Purity ≥99%
Available Mesh Sizes 200–500 Mesh
Standard Packaging 1 g / 5 g / 50 g

Product Description

A 211-type MAX phase is generally represented by M₂AX, where M is a transition metal, A is a main-group element, and X is C or N. Quaternary MAX phases typically incorporate two transition-metal elements at the M site. This design preserves the characteristic layered MAX-phase structure while providing additional scope for controlling elemental occupancy, lattice distortion, and material properties.

In this series, Al occupies the A site and C occupies the X site, while the M-site systems include combinations of V, Cr, Ti, Ta, Nb, and Mn. Actual elemental ratios, the degree of M-site ordering, primary-phase content, and secondary-phase composition should be confirmed using batch-specific XRD, elemental-analysis, and microscopic-characterization data.

Series Specifications

ParameterSeries Information
Product SeriesQuaternary MAX Phase (211) Research-Grade Powders
General Structural FormulaM₂AX; quaternary systems generally contain two transition-metal elements at the M site
Material TypeMulti-Metal M-Site Layered Carbides
A-Site ElementAl
X-Site ElementC
Product FormPowder
Product GradeResearch Grade
Nominal Purity≥99%
Available Mesh Sizes200, 300, 400, and 500 mesh, depending on the product model
Standard Packaging1 g, 5 g, and 50 g
Characterization DataBatch-specific XRD, SEM, EDS, and particle-size data may be available upon request
Customization ServicesSpecial mesh sizes, packaging, bulk quantities, and characterization requirements are available upon request
Inventory and Lead TimePlease inquire before ordering

Core Information Comparison Across the Full Product Series

Product ModelMaterial SystemM-Site ElementsA-Site ElementX-Site ElementComposition FeatureAvailable Mesh SizesRecommended Research Areas
VCrAlCVanadium Chromium Aluminum CarbideV and CrAlCV/Cr dual-M-site system200, 300, 400, and 500 meshElemental occupancy, magnetic and electrical properties, lattice regulation, and high-temperature performance
VTiAlCVanadium Titanium Aluminum CarbideV and TiAlCV/Ti dual-M-site system200, 300, 400, and 500 meshSolid-solution behavior, layered structures, electronic properties, and composite materials
TiTinAlCTiTin Aluminum Carbide Catalog ModelConfirm using batch documentationAlCCatalog formula retained as originally supplied200, 300, 400, and 500 meshElemental composition, crystal structure, phase composition, and interlayer bonding
TiVAlCTitanium Vanadium Aluminum CarbideTi and VAlCTi/V dual-M-site system200 and 400 meshLattice regulation, electronic structure, sintering, and functional properties
TiTaAlCTitanium Tantalum Aluminum CarbideTi and TaAlCTi/Ta dual-M-site system200 and 400 meshHigh-temperature stability, mechanical behavior, oxidation resistance, and heavy-element occupancy
TiNbAlCTitanium Niobium Aluminum CarbideTi and NbAlCTi/Nb dual-M-site system200 and 400 meshStructural stability, electrical and thermal properties, sintering, and composite materials
VNbAlCVanadium Niobium Aluminum CarbideV and NbAlCV/Nb dual-M-site system200 and 400 meshMulti-metal occupancy, electrochemistry, electronic structure, and derivative materials
VTaAlCVanadium Tantalum Aluminum CarbideV and TaAlCV/Ta dual-M-site system200 and 400 meshLattice distortion, high-temperature properties, electrical conduction, and interface studies
VMnAlCVanadium Manganese Aluminum CarbideV and MnAlCV/Mn dual-M-site system200 and 400 meshMagnetic behavior, electronic properties, elemental synergy, and functional materials
TiTinAlC is displayed exactly as provided in the supplied catalog model. Its exact elemental composition, stoichiometry, M-site elements, and crystal structure should be confirmed using the product label, batch-specific XRD data, and elemental-analysis documentation before purchase or experimentation.

Core Product Features

Dual-M-Site Design

Combining two transition-metal elements provides expanded opportunities for studying elemental occupancy and property regulation.

211-Type Layered Structure

Suitable for research on bonding, defects, and structural stability between M–X layers and Al layers.

Multiple Elemental Combinations

Includes V, Cr, Ti, Ta, Nb, and Mn systems for comparative studies across different transition-metal combinations.

Flexible Mesh Options

Available in 200–500 mesh grades for sintering, dispersion, composite preparation, and coating experiments.

Compatible with Multiple Processes

Suitable for pellet pressing, ball milling, hot pressing, spark-plasma sintering, and slurry preparation.

Batch Characterization Available

Batch-specific XRD, SEM, EDS, and particle-size data may be available upon request.

Typical Applications

Application AreaApplication Description
Fundamental Quaternary MAX-Phase ResearchCrystal structure, phase composition, lattice parameters, defects, and interlayer bonding
M-Site Occupancy ResearchDistribution and degree of ordering of two transition metals in the M-site sublattice
Element-Substitution ResearchComparison of how different transition-metal substitutions affect structural stability and material properties
Powder SinteringPressureless sintering, hot pressing, spark-plasma sintering, and densification studies
High-Temperature PerformanceThermal stability, oxidation resistance, thermal expansion, and high-temperature mechanical behavior
Composite MaterialsCombination with metals, ceramics, polymers, or carbon materials to study interfaces and reinforcement
Functional CoatingsWear-resistant, conductive, high-temperature-resistant, and oxidation-resistant coating formulations
Electrical and Magnetic ResearchElectrical conduction, electronic structure, magnetic response, and temperature-dependent transport
Layered Derivative MaterialsA-layer reactions, selective etching, and two-dimensional derivative-material exploration
Computational and Experimental ValidationComparison of first-principles calculations, structural predictions, and experimental results

Mesh Size and Packaging Selection

SpecificationKey CharacteristicsRecommended Uses
200 MeshRelatively coarse particles with good flowabilitySolid-state reactions, pellet pressing, sintering, and routine composite preparation
300 MeshBalances flowability and mixing uniformityFormulation screening, powder mixing, and routine material experiments
400 MeshFiner powder with a larger contact areaSlurries, coatings, dispersion, interfacial reactions, and fine mixing
500 MeshSuitable for higher-fineness requirementsFine coating, thin-layer preparation, and highly uniform dispersion
1 gSuitable for screening multiple models in small quantitiesPreliminary characterization, material selection, formulation validation, and small-scale trials
5 gSuitable for routine trials and process screeningSintering, composite preparation, coatings, and multiple performance tests
50 gSuitable for continuous experiments and staged R&DBatch mixing, sintering, and medium-quantity research experiments
Mesh size is a sieving specification and does not represent the complete particle-size distribution. When specific D10, D50, D90, or maximum-particle-size values are required, please review the data for the relevant batch.

Instructions for Use

ProcedureInstructions
Model SelectionSelect the product according to the M-site combination, research objective, mesh size, and required quantity
Batch VerificationBefore use, verify the product label, chemical formula, mesh size, and batch-specific characterization data
Opening and SamplingUse clean, dry tools and avoid moisture, oil contamination, and cross-contamination
Powder DryingFor moisture-sensitive experiments, pretreat under low-temperature vacuum or an inert atmosphere
Powder MixingUse mechanical stirring, low-energy ball milling, or another suitable method according to the formulation
DispersionFor slurry experiments, optimize the solvent, dispersant, stirring, and ultrasonication conditions
Pellet FormingPellet pressing may be performed before sintering; adjust pressure according to the equipment and powder condition
Heat TreatmentDetermine sintering temperature, atmosphere, heating rate, and holding time through preliminary trials
Sample PreparationPrepare bulk samples, composites, slurries, or functional coatings according to the research objective
Result CharacterizationAfter processing, use XRD, SEM, EDS, and relevant performance tests to confirm sample condition

Product Selection Guide

Research RequirementRecommended Model or Specification
V/Cr Dual-M-Site and Chromium-Effect ResearchVCrAlC
V/Ti Dual-M-Site and Solid-Solution ResearchVTiAlC or TiVAlC
Ti/Ta Dual-M-Site and High-Temperature ResearchTiTaAlC
Ti/Nb Dual-M-Site and Structural-Stability ResearchTiNbAlC
V/Nb Dual-M-Site and Electronic-Property ResearchVNbAlC
V/Ta Dual-M-Site and Lattice-Distortion ResearchVTaAlC
V/Mn Dual-M-Site and Magnetic-Property ResearchVMnAlC
Sintering and Pellet-Pressing ExperimentsPrioritize 200 or 300 mesh
Slurries, Coatings, and Fine DispersionPrioritize 400 or 500 mesh
Preliminary Screening of Multiple ModelsChoose 1 g packages

Recommended Characterization

Characterization MethodPrimary Purpose
XRDConfirm the primary MAX phase, crystal structure, lattice parameters, and possible secondary phases
SEMObserve particle morphology, surface condition, layered features, and agglomeration
TEM / STEMObserve local lattice, interlayer structures, defects, interfaces, and M-site occupancy
EDSAnalyze elemental composition, elemental ratios, and spatial-distribution uniformity
XPSAnalyze surface chemical states and bonding between different elements
Particle-Size AnalysisDetermine D10, D50, D90, and the complete particle-size distribution
Thermal AnalysisStudy thermal stability, oxidation processes, mass changes, and thermal behavior
Electrical TestingStudy electrical resistivity, conduction behavior, and temperature-dependent transport
Magnetic TestingStudy magnetic response and temperature-dependent magnetic behavior in Cr- or Mn-containing systems
Quantitative Elemental AnalysisVerify the actual ratio and stoichiometry of the two M-site elements

Storage and Safety

ItemRecommendation
Storage EnvironmentStore sealed in a cool, dry place away from direct light
Storage After OpeningReseal promptly after sampling and avoid prolonged exposure to air and moisture
Long-Term StorageVacuum or inert-gas protection may be used when required
Personal ProtectionWear laboratory gloves, a dust mask or suitable respirator, protective clothing, and safety goggles
Dust ControlAvoid generating airborne dust and operate in a fume hood or under local dust extraction
Cross-ContaminationUse dedicated or thoroughly cleaned sampling, grinding, and mixing tools for different models
Waste DisposalDispose of the material according to laboratory requirements for inorganic powders and metal-containing waste
Intended UseFor scientific research and industrial R&D only; not intended for food, medical, or human-use applications

Frequently Asked Questions

1. What is a quaternary 211-type MAX phase?
A 211-type MAX phase is generally represented by M₂AX. In a quaternary system, two transition-metal elements are typically introduced at the M site, so the material contains two M elements, one A element, and one X element. This design can be used to regulate lattice parameters, elemental occupancy, interlayer bonding, and related properties.
2. Are the two M-site elements necessarily distributed in equal proportions?
Not necessarily. The catalog formula indicates the primary composition, but actual elemental ratios, the degree of M-site ordering, and spatial distribution may depend on raw-material ratios and synthesis conditions. When the M-site ratio is critical, evaluate batch-specific quantitative elemental analysis, EDS, or atomic-scale characterization.
3. Which elements does TiTinAlC represent?
This page preserves the supplied catalog model name “TiTinAlC” exactly as provided. The second M-site element and the precise stoichiometry cannot be determined reliably from this string alone. Product labels, batch reports, and supplier documentation should be checked before purchase or experimentation.
4. How should I choose among 200, 300, 400, and 500 mesh?
The 200- and 300-mesh grades are generally suitable for solid-state reactions, pellet pressing, and sintering. The 400-mesh grade is suitable for slurries, coatings, and fine mixing. The 500-mesh grade is suitable for higher-fineness dispersion and thin-layer preparation. Mesh size is a sieving specification and does not represent the complete particle-size distribution.
5. Does nominal purity ≥99% mean that the primary MAX-phase content is also ≥99%?
Not necessarily. Chemical purity and phase purity are different specifications. When strict requirements apply to primary MAX-phase content, secondary phases, M-site occupancy, or actual stoichiometry, review batch-specific XRD, elemental-analysis, SEM, and other characterization data.

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Quaternary MAX Phase (211) Specifications / Price List

Research-Grade Powder ' Purity ≥99% ' 200–500 Mesh Available ' 1 g, 5 g, and 50 g Options

Product ModelMesh Size1 g5 g50 g
VCrAlC200 Mesh$33$150$1,275
300 Mesh$34$153$1,301
400 Mesh$35$156$1,326
500 Mesh$35$159$1,352
VTiAlC200 Mesh$40$180$1,530
300 Mesh$41$183$1,556
400 Mesh$41$186$1,581
500 Mesh$42$189$1,607
TiTinAlC200 Mesh$50$225$1,913
300 Mesh$51$228$1,938
400 Mesh$51$231$1,964
500 Mesh$52$234$1,989
TiVAlC200 Mesh$70$194$1,648
400 Mesh$74$193$1,642
TiTaAlC200 Mesh$70$194$1,648
400 Mesh$74$193$1,642
TiNbAlC200 Mesh$70$232$1,968
400 Mesh$74$239$2,029
VNbAlC200 Mesh$70$194$1,648
400 Mesh$74$193$1,642
VTaAlC200 Mesh$70$194$1,648
400 Mesh$74$193$1,642
VMnAlC200 Mesh$70$194$1,648
400 Mesh$74$193$1,642

Partial references citing our materials (from Google Scholar)


Carbon Dioxide Reduction

1. ACS Nano Strain Relaxation in Metal Alloy Catalysts Steers the Product Selectivity of Electrocatalytic CO2 Reduction

The bipolar membrane (Fumasep FBM) in this paper was purchased from SCI Materials Hub, which was used in rechargeable Zn-CO2 battery tests. The authors reported a strain relaxation strategy to determine lattice strains in bimetal MNi alloys (M = Pd, Ag, and Au) and realized an outstanding CO2-to-CO Faradaic efficiency of 96.6% with outstanding activity and durability toward a Zn-CO2 battery.


2. Front. Chem. Boosting Electrochemical Carbon Dioxide Reduction on Atomically Dispersed Nickel Catalyst

In this paper, Vulcan XC-72R was purchased from SCI Materials Hub. Vulcan XC 72R carbon is the most common catalyst support used in the anode and cathode electrodes of Polymer Electrolyte Membrane Fuel Cells (PEMFC), Direct Methanol Fuel Cells (DMFC), Alkaline Fuel Cells (AFC), Microbial Fuel Cells (MFC), Phosphoric Acid Fuel Cells (PAFC), and many more!


3. Adv. Mater. Partially Nitrided Ni Nanoclusters Achieve Energy-Efficient Electrocatalytic CO2 Reduction to CO at Ultralow Overpotential

An AEM membrane (Sustainion X37-50 Grade RT, purchased from SCI Materials Hub) was activated in 1 M KOH for 24 h, washed with ultra-purity water prior to use.


4. Adv. Funct. Mater. Nanoconfined Molecular Catalysts in Integrated Gas Diffusion Electrodes for High-Current-Density CO2 Electroreduction

In this paper (Supporting Information), an anion exchanged membrane (Fumasep FAB-PK-130 obtained from SCI Materials Hub (www.scimaterials.cn)) was used to separate the catholyte and anolyte chambers.

SCI Materials Hub: we also recommend our Fumasep FAB-PK-75 for the use in a flow cell.


5. Appl. Catal. B Efficient utilization of nickel single atoms for CO2 electroreduction by constructing 3D interconnected nitrogen-doped carbon tube network

In this paper, the Nafion 117 membrane was obtained from SCI Materials Hub.


6. Vacuum Modulable Cu(0)/Cu(I)/Cu(II) sites of Cu/C catalysts derived from MOF for highly selective CO2 electroreduction to hydrocarbons

In this paper, Proton exchange membrane (Nafion 117), Nafion D520, and Toray 060 carbon paper were purchased from SCI Materials Hub.


7. National Science Review Confinement of ionomer for electrocatalytic CO2 reduction reaction via efficient mass transfer pathways

An anion exchange membrane (PiperION-A15-HCO3) was obtained from SCI Materials Hub.


8. Catalysis Communications Facilitating CO2 electroreduction to C2H4 through facile regulating {100} & {111} grain boundary of Cu2O

Carbon paper (TGPH060), membrane solution (Nafion D520), and ionic membrane (Nafion N117) were obtained from Wuhu Eryi Material Technology Co., Ltd (a company under SCI Materials Hub).


Batteries

1. J. Mater. Chem. A Blocking polysulfides with a Janus Fe3C/N-CNF@RGO electrode via physiochemical confinement and catalytic conversion for high-performance lithium–sulfur batteries

Graphene oxide (GO) in this paper was obtained from SCI Materials Hub. The authors introduced a Janus Fe3C/N-CNF@RGO electrode consisting of 1D Fe3C decorated N-doped carbon nanofibers (Fe3C/N-CNFs) side and 2D reduced graphene oxide (RGO) side as the free-standing carrier of Li2S6 catholyte to improve the overall electrochemical performance of Li-S batteries.


2. Joule A high-voltage and stable zinc-air battery enabled by dual-hydrophobic-induced proton shuttle shielding

This paper used more than 10 kinds of materials from SCI Materials Hub and the authors gave detailed properity comparsion.

The commercial IEMs of Fumasep FAB-PK-130 and Nafion N117 were obtained from SCI Materials Hub.

Gas diffusion layers of GDL340 (CeTech) and SGL39BC (Sigracet) and Nafion dispersion (Nafion D520) were obtained from SCI Materials Hub.

Zn foil (100 mm thickness) and Zn powder were obtained from the SCI Materials Hub.

Commercial 20% Pt/C, 40% Pt/C and IrO2 catalysts were also obtained from SCI Materials Hub.


3. Journal of Energy Chemistry Vanadium oxide nanospheres encapsulated in N-doped carbon nanofibers with morphology and defect dual-engineering toward advanced aqueous zinc-ion batteries

In this paper, carbon cloth (W0S1011) was obtained from SCI Materials Hub. The flexible carbon cloth matrix guaranteed the stabilization of the electrode and improved the conductivity of the cathode.


4. Energy Storage Materials Defect-abundant commercializable 3D carbon papers for fabricating composite Li anode with high loading and long life

The 3D carbon paper (TGPH060 raw paper) were purchased from SCI Materials Hub.


5. Nanomaterials A Stable Rechargeable Aqueous Zn–Air Battery Enabled by Heterogeneous MoS2 Cathode Catalysts

Nafion D520 (5 wt%), and carbon paper (GDL340) were received from SCI-Materials-Hub.


6. SSRN An Axially Directed Cobalt-Phthalocyanine Covalent Organic Polymer as High-Efficient Bifunctional Catalyst for Zn-Air Battery

Carbon cloth (W0S1011) and other electrochemical consumables required for air cathode were provided by SCI Materials Hub.


Oxygen Reduction Reaction

1. J. Chem. Eng. Superior Efficiency Hydrogen Peroxide Production in Acidic Media through Epoxy Group Adjacent to Co-O/C Active Centers on Carbon Black

In this paper, Vulcan XC 72 carbon black, ion membrane (Nafion N115, 127 μL), Nafion solution (D520, 5 wt%), and carbon paper (AvCarb GDS 2230 and Spectracarb 2050A-1050) were purchased from SCI Materials Hub.


2. Journal of Colloid and Interface Science Gaining insight into the impact of electronic property and interface electrostatic field on ORR kinetics in alloy engineering via theoretical prognostication and experimental validation

The 20 wt% Pt3M (M = Cr, Co, Cu, Pd, Sn, and Ir) were purchased from SCI Materials Hub. This work places emphasis on the kinetics of the ORR concerning Pt3M (M = Cr, Co, Cu, Pd, Sn, and Ir) catalysts, and integrates theoretical prognostication and experimental validation to illuminate the fundamental principles of alloy engineering.


Water Electrolysis

1. International Journal of Hydrogen Energy Gold as an efficient hydrogen isotope separation catalyst in proton exchange membrane water electrolysis

The cathodic catalysts of Pt/C (20 wt%, 2–3 nm) and Au/C (20 wt%, 4–5 nm) were purchased from SCI Materials Hub.


2. Small Science Silver Compositing Boosts Water Electrolysis Activity and Durability of RuO2 in a Proton-Exchange-Membrane Water Electrolyzer

Two fiber felts (0.35 mm thickness, SCI Materials Hub) were used as the porous transport layers at both the cathode and the anode.


3. Advanced Functional Materials Hierarchical Crystalline/Amorphous Heterostructure MoNi/NiMoOx for Electrochemical Hydrogen Evolution with Industry-Level Activity and Stability

Anion-exchange membrane (FAA-3-PK-130) was obtained from SCI Materials Hub website.


Fuel Cells

1. Polymer Sub-two-micron ultrathin proton exchange membrane with reinforced mechanical strength

Gas diffusion electrode (60% Pt/C, Carbon paper) was purchased from SCI Materials Hub.


Characterization

1. Chemical Engineering Journal Electrochemical reconstitution of Prussian blue analogue for coupling furfural electro-oxidation with photo-assisted hydrogen evolution reaction

An Au nanoparticle film was deposited on the total reflecting plane of a single reflection ATR crystal (SCI Materials Hub, Wuhu, China) via sputter coater.

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