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SciMater™ Research-Grade Quaternary MAX Phase Powder (413 Series)

  • Product Code:Mo2V2AlC3, Mo2Nb2AlC3, Mo2Ti2AlC3, Ti2V2AlC3, Ti2Ta2AlC3
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  • Brand:SciMater™
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  • Keywords:SciMater™ Research-Grade Quaternary MAX Phase Powder (413 Series), SCI Materials Hub
SciMater™ QUATERNARY MAX PHASE MATERIALS

Quaternary MAX Phase (413) Research-Grade Powders

Dual-M-Site Layered Carbides | Nominal Purity ≥99% | 200, 400, and 600 Mesh Options | Standard Packaging: 1 g, 5 g, and 50 g

Quaternary MAX Phase (413) Research-Grade Powder Purity ≥99% 5 Product Models Dual-M-Site Carbides

This series includes Mo₂V₂AlC₃, Mo₂Nb₂AlC₃, Mo₂Ti₂AlC₃, Ti₂V₂AlC₃, and Ti₂Ta₂AlC₃. These materials are suitable for studies of dual-M-site occupancy, lattice regulation, interlayer bonding, powder sintering, composite materials, functional coatings, high-temperature performance, and layered derivative materials.

Product Series Quaternary MAX (413)
Nominal Purity ≥99%
Available Mesh Sizes 200–600 Mesh
Standard Packaging 1 g / 5 g / 50 g

Product Description

A 413-type MAX phase is generally represented by M₄AX₃, where M is a transition metal, A is a main-group element, and X is C or N. Quaternary 413-type MAX phases usually contain two transition-metal elements sharing the M site. This design preserves the characteristic layered MAX-phase structure while providing additional variables for elemental occupancy, lattice modification, interlayer bonding, and property regulation.

In this series, Al occupies the A site and C occupies the X site, while the dual-M-site systems include Mo/V, Mo/Nb, Mo/Ti, Ti/V, and Ti/Ta. Actual elemental distribution, the degree of M-site ordering, primary-phase content, crystal structure, and secondary phases should be confirmed using batch-specific XRD, elemental-analysis, and microscopic-characterization data.

Series Specifications

ParameterSeries Information
Product SeriesQuaternary MAX Phase (413) Research-Grade Powders
General Structural FormulaM₄AX₃; quaternary systems generally contain two transition-metal elements at the M site
Material TypeDual-M-Site Layered Carbides
A-Site ElementAl
X-Site ElementC
Product FormPowder
Product GradeResearch Grade
Nominal Purity≥99%
Available Mesh Sizes200, 400, and 600 mesh, depending on the product model
Standard Packaging1 g, 5 g, and 50 g
Characterization DataBatch-specific XRD, SEM, EDS, and particle-size data may be available upon request
Customization ServicesSpecial mesh sizes, packaging, bulk quantities, and characterization requirements are available upon request
Inventory and Lead TimePlease inquire before ordering

Core Information Comparison Across the Full Product Series

Product ModelMaterial SystemM-Site ElementsA-Site ElementX-Site ElementComposition FeatureAvailable Mesh SizesRecommended Research Areas
Mo₂V₂AlC₃Molybdenum Vanadium Aluminum CarbideMo and VAlCMo/V dual-M-site 413 system200, 400, and 600 meshM-site occupancy, electronic structure, electrochemistry, lattice regulation, and layered derivative materials
Mo₂Nb₂AlC₃Molybdenum Niobium Aluminum CarbideMo and NbAlCMo/Nb dual-M-site 413 system200, 400, and 600 meshStructural stability, elemental occupancy, electrical and thermal properties, and composite materials
Mo₂Ti₂AlC₃Molybdenum Titanium Aluminum CarbideMo and TiAlCMo/Ti dual-M-site 413 system200 and 400 meshM-site ordering, interlayer bonding, crystal structure, electronic properties, and sintering
Ti₂V₂AlC₃Titanium Vanadium Aluminum CarbideTi and VAlCTi/V dual-M-site 413 system200 and 400 meshElemental substitution, lattice variation, electrochemistry, electrical conduction, and interface properties
Ti₂Ta₂AlC₃Titanium Tantalum Aluminum CarbideTi and TaAlCTi/Ta dual-M-site 413 system200 and 400 meshHigh-temperature stability, oxidation resistance, mechanical behavior, heavy-element occupancy, and composites
Catalog formulas indicate the primary composition. Actual ratios, ordering, spatial arrangement, primary-phase content, and secondary phases of the two M-site elements should be confirmed using batch-specific XRD, quantitative elemental analysis, and microscopic characterization.

Core Product Features

Dual-M-Site Design

Two transition-metal elements share the M site, providing additional variables for elemental occupancy and property regulation.

413-Type Layered Structure

Suitable for research on relatively thick M–C layers, Al-layer bonding, interlayer structures, and stability changes.

Multiple Transition-Metal Combinations

Includes Mo, V, Nb, Ti, and Ta systems for comparative studies across different dual-M-site combinations.

Multiple Mesh Options

Available in 200, 400, and 600 mesh grades for sintering, dispersion, and coating experiments.

Compatible with Multiple Processing Routes

Suitable for pellet pressing, hot pressing, spark-plasma sintering, slurry preparation, and composite fabrication.

Batch Documentation Available

Batch-specific XRD, SEM, EDS, and particle-size data may be available upon request.

Typical Applications

Application AreaApplication Description
Fundamental Quaternary MAX-Phase ResearchCrystal structure, phase composition, lattice parameters, defects, and interlayer bonding
M-Site Occupancy ResearchDistribution, degree of ordering, and synergistic effects of two transition metals in the M-site sublattice
Element-Substitution ResearchComparison of how different transition-metal combinations affect lattice parameters, stability, and material properties
Powder SinteringPressureless sintering, hot pressing, spark-plasma sintering, and densification studies
High-Temperature PerformanceThermal stability, oxidation behavior, thermal expansion, and high-temperature mechanical properties
Composite MaterialsCombination with metals, ceramics, polymers, or carbon materials to study interfaces and reinforcement effects
Functional CoatingsConductive, wear-resistant, high-temperature-resistant, and oxidation-resistant coating formulations
Electrical and Electrochemical ResearchElectronic structure, electrical conduction, electrochemical response, and interfacial reactions
Layered Derivative MaterialsA-layer reactions, structural evolution, and two-dimensional layered derivative materials
Computational and Experimental ValidationComparison of first-principles calculations, structural predictions, and experimental results

Mesh Size and Packaging Selection

SpecificationKey CharacteristicsRecommended Uses
200 MeshRelatively coarse particles with good flowabilitySolid-state reactions, pellet pressing, sintering, and routine composite preparation
400 MeshFiner powder with a relatively larger contact areaSlurries, coatings, dispersion, interfacial reactions, and fine mixing
600 MeshHigher fineness for demanding dispersion and mixing requirementsFine coating, thin-layer preparation, and highly uniform formulations
1 gSuitable for screening multiple models in small quantitiesPreliminary characterization, material selection, formulation validation, and small-scale trials
5 gSuitable for routine trials and process screeningSintering, composite preparation, coatings, and multiple performance tests
50 gSuitable for continuous experiments and staged R&DBatch mixing, sintering, and medium-quantity research experiments
Mesh size is a sieving specification and does not represent the complete particle-size distribution. When specific D10, D50, D90, or maximum-particle-size values are required, please review the data for the relevant batch.

Instructions for Use

ProcedureInstructions
Model SelectionSelect the product according to the M-site combination, research objective, mesh size, and required quantity
Batch VerificationBefore use, verify the product label, chemical formula, mesh size, and batch-specific characterization data
Opening and SamplingUse clean, dry tools and avoid moisture, oil contamination, and cross-contamination
PretreatmentFor moisture-sensitive experiments, low-temperature vacuum drying or inert-atmosphere drying may be used
Powder MixingUse mechanical stirring, low-energy ball milling, or another suitable method according to the formulation
DispersionFor slurry experiments, optimize the solvent, dispersant, stirring, and ultrasonication conditions
Pellet FormingPellet pressing may be performed before sintering; adjust pressure according to the equipment and powder condition
Heat TreatmentDetermine sintering temperature, atmosphere, heating rate, and holding time through preliminary trials
Sample PreparationPrepare bulk samples, composites, slurries, or functional coatings according to the research objective
Result CharacterizationAfter processing, use XRD, SEM, EDS, and relevant performance tests to confirm sample condition

Product Selection Guide

Research RequirementRecommended Model or Specification
Mo/V Dual-M-Site and Electrochemical-Property ResearchMo₂V₂AlC₃
Mo/Nb Dual-M-Site and Structural-Stability ResearchMo₂Nb₂AlC₃
Mo/Ti Dual-M-Site and Ordered-Structure ResearchMo₂Ti₂AlC₃
Ti/V Dual-M-Site and Electronic-Property ResearchTi₂V₂AlC₃
Ti/Ta Dual-M-Site and High-Temperature ResearchTi₂Ta₂AlC₃
Sintering, Pellet Pressing, and Solid-State ReactionsPrioritize 200 mesh
Slurries, Coatings, and Fine DispersionPrioritize 400 mesh
Higher-Fineness Coating and DispersionPrioritize available 600-mesh products
Preliminary Screening of Multiple ModelsChoose 1 g packages
Continuous Experiments and Staged R&DChoose 5 g or 50 g packages

Recommended Characterization

Characterization MethodPrimary Purpose
XRDConfirm the primary MAX phase, crystal structure, lattice parameters, and possible secondary phases
SEMObserve particle morphology, surface condition, layered features, and agglomeration
TEM / STEMObserve local lattice, interlayer structures, defects, interfaces, and M-site occupancy
EDSAnalyze elemental composition, elemental ratios, and spatial-distribution uniformity
XPSAnalyze surface chemical states and bonding between different elements
Particle-Size AnalysisDetermine D10, D50, D90, and the complete particle-size distribution
Thermal AnalysisStudy thermal stability, oxidation processes, mass changes, and thermal behavior
Electrical TestingStudy electrical resistivity, conduction behavior, and temperature-dependent transport
Mechanical TestingStudy hardness, elasticity, indentation, fracture, and damage behavior
Quantitative Elemental AnalysisVerify the actual ratio and stoichiometry of the two M-site elements

Storage and Safety

ItemRecommendation
Storage EnvironmentStore sealed in a cool, dry place away from direct light
Storage After OpeningReseal promptly after sampling and avoid prolonged exposure to air and moisture
Long-Term StorageVacuum or inert-gas protection may be used when required
Personal ProtectionWear laboratory gloves, a dust mask or suitable respirator, protective clothing, and safety goggles
Dust ControlAvoid generating airborne dust and operate in a fume hood or under local dust extraction
Cross-ContaminationUse dedicated or thoroughly cleaned sampling, grinding, and mixing tools for different models
Waste DisposalDispose of the material according to laboratory requirements for inorganic powders and metal-containing waste
Intended UseFor scientific research and industrial R&D only; not intended for food, medical, or human-use applications

Frequently Asked Questions

1. What is a quaternary 413-type MAX phase?
A 413-type MAX phase is generally represented by M₄AX₃. In a quaternary system, two transition-metal elements are typically introduced at the M site, so the material contains two M elements, one A element, and one X element. This design can be used to regulate lattice parameters, elemental occupancy, interlayer bonding, and related properties.
2. Are the two M-site elements necessarily ordered?
Not necessarily. The catalog formula indicates the primary elemental composition, but the two M elements may exhibit ordered occupancy, partial ordering, or solid-solution distribution. Their precise arrangement should be determined using XRD refinement, STEM, EDS, or other structural-characterization methods.
3. How should I choose among 200, 400, and 600 mesh?
The 200-mesh grade is generally suitable for solid-state reactions, pellet pressing, and sintering. The 400-mesh grade is suitable for slurries, coatings, fine mixing, and dispersion. The 600-mesh grade is suitable for experiments requiring higher fineness and more uniform mixing. Mesh size is a sieving specification and does not represent the complete particle-size distribution.
4. Can quaternary 413-type MAX phases be used for two-dimensional layered derivative-material research?
They can be used for exploratory studies of A-layer reactions, selective removal, and two-dimensional derivative materials. However, reaction activity, product structure, surface terminations, and delamination behavior may vary among models. Preliminary trials should be used to determine the reaction system, temperature, duration, and post-treatment conditions.
5. Does nominal purity ≥99% mean that the primary MAX-phase content is also ≥99%?
Not necessarily. Chemical purity and phase purity are different specifications. When strict requirements apply to primary MAX-phase content, secondary phases, M-site occupancy, or actual stoichiometry, review batch-specific XRD, elemental-analysis, SEM, and other characterization data.

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Quaternary MAX Phase (413) Specifications / Price List

Research-Grade Powder ' Purity ≥99% ' 200, 400, and 600 Mesh Available ' 1 g, 5 g, and 50 g Options

Product ModelMesh Size1 g5 g50 g
Mo₂V₂AlC₃200 Mesh$60$253$2,153
400 Mesh$63$255$2,168
600 Mesh$67$270$2,295
Mo₂Nb₂AlC₃200 Mesh$60$253$2,153
400 Mesh$63$255$2,168
600 Mesh$67$270$2,295
Mo₂Ti₂AlC₃200 Mesh$39$174$720
400 Mesh$44$200$833
Ti₂V₂AlC₃200 Mesh$70$194$1,648
400 Mesh$74$193$1,642
Ti₂Ta₂AlC₃200 Mesh$70$194$1,648
400 Mesh$74$193$1,642

Partial references citing our materials (from Google Scholar)


Carbon Dioxide Reduction

1. ACS Nano Strain Relaxation in Metal Alloy Catalysts Steers the Product Selectivity of Electrocatalytic CO2 Reduction

The bipolar membrane (Fumasep FBM) in this paper was purchased from SCI Materials Hub, which was used in rechargeable Zn-CO2 battery tests. The authors reported a strain relaxation strategy to determine lattice strains in bimetal MNi alloys (M = Pd, Ag, and Au) and realized an outstanding CO2-to-CO Faradaic efficiency of 96.6% with outstanding activity and durability toward a Zn-CO2 battery.


2. Front. Chem. Boosting Electrochemical Carbon Dioxide Reduction on Atomically Dispersed Nickel Catalyst

In this paper, Vulcan XC-72R was purchased from SCI Materials Hub. Vulcan XC 72R carbon is the most common catalyst support used in the anode and cathode electrodes of Polymer Electrolyte Membrane Fuel Cells (PEMFC), Direct Methanol Fuel Cells (DMFC), Alkaline Fuel Cells (AFC), Microbial Fuel Cells (MFC), Phosphoric Acid Fuel Cells (PAFC), and many more!


3. Adv. Mater. Partially Nitrided Ni Nanoclusters Achieve Energy-Efficient Electrocatalytic CO2 Reduction to CO at Ultralow Overpotential

An AEM membrane (Sustainion X37-50 Grade RT, purchased from SCI Materials Hub) was activated in 1 M KOH for 24 h, washed with ultra-purity water prior to use.


4. Adv. Funct. Mater. Nanoconfined Molecular Catalysts in Integrated Gas Diffusion Electrodes for High-Current-Density CO2 Electroreduction

In this paper (Supporting Information), an anion exchanged membrane (Fumasep FAB-PK-130 obtained from SCI Materials Hub (www.scimaterials.cn)) was used to separate the catholyte and anolyte chambers.

SCI Materials Hub: we also recommend our Fumasep FAB-PK-75 for the use in a flow cell.


5. Appl. Catal. B Efficient utilization of nickel single atoms for CO2 electroreduction by constructing 3D interconnected nitrogen-doped carbon tube network

In this paper, the Nafion 117 membrane was obtained from SCI Materials Hub.


6. Vacuum Modulable Cu(0)/Cu(I)/Cu(II) sites of Cu/C catalysts derived from MOF for highly selective CO2 electroreduction to hydrocarbons

In this paper, Proton exchange membrane (Nafion 117), Nafion D520, and Toray 060 carbon paper were purchased from SCI Materials Hub.


7. National Science Review Confinement of ionomer for electrocatalytic CO2 reduction reaction via efficient mass transfer pathways

An anion exchange membrane (PiperION-A15-HCO3) was obtained from SCI Materials Hub.


8. Catalysis Communications Facilitating CO2 electroreduction to C2H4 through facile regulating {100} & {111} grain boundary of Cu2O

Carbon paper (TGPH060), membrane solution (Nafion D520), and ionic membrane (Nafion N117) were obtained from Wuhu Eryi Material Technology Co., Ltd (a company under SCI Materials Hub).


Batteries

1. J. Mater. Chem. A Blocking polysulfides with a Janus Fe3C/N-CNF@RGO electrode via physiochemical confinement and catalytic conversion for high-performance lithium–sulfur batteries

Graphene oxide (GO) in this paper was obtained from SCI Materials Hub. The authors introduced a Janus Fe3C/N-CNF@RGO electrode consisting of 1D Fe3C decorated N-doped carbon nanofibers (Fe3C/N-CNFs) side and 2D reduced graphene oxide (RGO) side as the free-standing carrier of Li2S6 catholyte to improve the overall electrochemical performance of Li-S batteries.


2. Joule A high-voltage and stable zinc-air battery enabled by dual-hydrophobic-induced proton shuttle shielding

This paper used more than 10 kinds of materials from SCI Materials Hub and the authors gave detailed properity comparsion.

The commercial IEMs of Fumasep FAB-PK-130 and Nafion N117 were obtained from SCI Materials Hub.

Gas diffusion layers of GDL340 (CeTech) and SGL39BC (Sigracet) and Nafion dispersion (Nafion D520) were obtained from SCI Materials Hub.

Zn foil (100 mm thickness) and Zn powder were obtained from the SCI Materials Hub.

Commercial 20% Pt/C, 40% Pt/C and IrO2 catalysts were also obtained from SCI Materials Hub.


3. Journal of Energy Chemistry Vanadium oxide nanospheres encapsulated in N-doped carbon nanofibers with morphology and defect dual-engineering toward advanced aqueous zinc-ion batteries

In this paper, carbon cloth (W0S1011) was obtained from SCI Materials Hub. The flexible carbon cloth matrix guaranteed the stabilization of the electrode and improved the conductivity of the cathode.


4. Energy Storage Materials Defect-abundant commercializable 3D carbon papers for fabricating composite Li anode with high loading and long life

The 3D carbon paper (TGPH060 raw paper) were purchased from SCI Materials Hub.


5. Nanomaterials A Stable Rechargeable Aqueous Zn–Air Battery Enabled by Heterogeneous MoS2 Cathode Catalysts

Nafion D520 (5 wt%), and carbon paper (GDL340) were received from SCI-Materials-Hub.


6. SSRN An Axially Directed Cobalt-Phthalocyanine Covalent Organic Polymer as High-Efficient Bifunctional Catalyst for Zn-Air Battery

Carbon cloth (W0S1011) and other electrochemical consumables required for air cathode were provided by SCI Materials Hub.


Oxygen Reduction Reaction

1. J. Chem. Eng. Superior Efficiency Hydrogen Peroxide Production in Acidic Media through Epoxy Group Adjacent to Co-O/C Active Centers on Carbon Black

In this paper, Vulcan XC 72 carbon black, ion membrane (Nafion N115, 127 μL), Nafion solution (D520, 5 wt%), and carbon paper (AvCarb GDS 2230 and Spectracarb 2050A-1050) were purchased from SCI Materials Hub.


2. Journal of Colloid and Interface Science Gaining insight into the impact of electronic property and interface electrostatic field on ORR kinetics in alloy engineering via theoretical prognostication and experimental validation

The 20 wt% Pt3M (M = Cr, Co, Cu, Pd, Sn, and Ir) were purchased from SCI Materials Hub. This work places emphasis on the kinetics of the ORR concerning Pt3M (M = Cr, Co, Cu, Pd, Sn, and Ir) catalysts, and integrates theoretical prognostication and experimental validation to illuminate the fundamental principles of alloy engineering.


Water Electrolysis

1. International Journal of Hydrogen Energy Gold as an efficient hydrogen isotope separation catalyst in proton exchange membrane water electrolysis

The cathodic catalysts of Pt/C (20 wt%, 2–3 nm) and Au/C (20 wt%, 4–5 nm) were purchased from SCI Materials Hub.


2. Small Science Silver Compositing Boosts Water Electrolysis Activity and Durability of RuO2 in a Proton-Exchange-Membrane Water Electrolyzer

Two fiber felts (0.35 mm thickness, SCI Materials Hub) were used as the porous transport layers at both the cathode and the anode.


3. Advanced Functional Materials Hierarchical Crystalline/Amorphous Heterostructure MoNi/NiMoOx for Electrochemical Hydrogen Evolution with Industry-Level Activity and Stability

Anion-exchange membrane (FAA-3-PK-130) was obtained from SCI Materials Hub website.


Fuel Cells

1. Polymer Sub-two-micron ultrathin proton exchange membrane with reinforced mechanical strength

Gas diffusion electrode (60% Pt/C, Carbon paper) was purchased from SCI Materials Hub.


Characterization

1. Chemical Engineering Journal Electrochemical reconstitution of Prussian blue analogue for coupling furfural electro-oxidation with photo-assisted hydrogen evolution reaction

An Au nanoparticle film was deposited on the total reflecting plane of a single reflection ATR crystal (SCI Materials Hub, Wuhu, China) via sputter coater.

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