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SciMater™ Research-Grade Quaternary i-MAX Phase Powder (211 Series)

  • Product Code:(Mo2/3Y1/3)2AlC, (Mo2/3Sc1/3)2AlC
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SciMater™ IN-PLANE ORDERED MAX PHASE MATERIALS

Research-Grade Quaternary i-MAX Phase Powders (211 Series)

In-Plane Ordered Multi-Metal MAX Phases | 200 and 400 Mesh Options | Standard Packaging: 1 g, 5 g, and 50 g

i-MAX Phase (211) Research-Grade Powder Mo/Y and Mo/Sc Systems 2 Product Models 2D Derivative Precursors

This series includes (Mo2/3Y1/3)2AlC and (Mo2/3Sc1/3)2AlC. These materials are suitable for research on i-MAX crystal structures, in-plane M-site ordering, elemental occupancy, interlayer bonding, powder sintering, selective reactions, and two-dimensional layered derivative materials.

Product Series i-MAX Phase (211)
Product Models 2 Models
Available Mesh Sizes 200 / 400 Mesh
Standard Packaging 1 g / 5 g / 50 g

Product Description

i-MAX phases are multi-metal systems derived from the layered structure of conventional MAX phases. The letter “i” generally indicates that the transition-metal atoms exhibit a specific in-plane ordering pattern within the M layers. These materials usually contain two M-site elements with different atomic sizes or chemical characteristics and are suitable for studying M-site arrangement, local lattice distortion, interlayer bonding, and selective-reaction behavior.

In this series, Mo is the primary M-site element, while Y or Sc is introduced to form the nominal composition (Mo2/3M′1/3)2AlC. Catalog formulas indicate nominal composition only. The actual degree of M-site ordering, primary-phase content, elemental distribution, and secondary-phase composition should be confirmed using batch-specific XRD, elemental analysis, and microscopic structural characterization.

Series Specifications

ParameterSeries Information
Product Seriesi-MAX Phase (211) Research-Grade Powders
Nominal Structural Formula(Mo2/3M′1/3)2AlC, where M′ is Y or Sc
Material TypeIn-Plane Ordered Multi-Metal Layered Carbides
Primary M-Site ElementsMo and Y, or Mo and Sc
A-Site ElementAl
X-Site ElementC
Product FormPowder
Product GradeResearch Grade
Nominal PurityY-containing system: ≥99%; Sc-containing system: not specified and should be confirmed before purchase
Available Mesh Sizes200 and 400 mesh
Standard Packaging1 g, 5 g, and 50 g
Characterization DataBatch-specific XRD, SEM, EDS, particle-size, and related documentation may be available upon request
Customization ServicesSpecial mesh sizes, packaging, bulk quantities, and characterization requirements are available upon request
Inventory and Lead TimePlease inquire before ordering

Core Information Comparison Across the Full Product Series

Product ModelMaterial SystemM-Site ElementsA-Site ElementX-Site ElementNominal M-Site RatioAvailable Mesh SizesRecommended Research Areas
(Mo2/3Y1/3)2AlCMo/Y-Type i-MAX PhaseMo and YAlCMo:Y = 2:1200 and 400 meshIn-plane ordering, elemental occupancy, lattice distortion, selective reactions, and two-dimensional derivative materials
(Mo2/3Sc1/3)2AlCMo/Sc-Type i-MAX PhaseMo and ScAlCMo:Sc = 2:1200 and 400 meshIn-plane ordering, local structures, M-site arrangement, interfacial reactions, and two-dimensional derivative materials
Chemical formulas indicate nominal composition and do not guarantee complete M-site ordering. Actual elemental ratios, degree of ordering, lattice parameters, primary-phase content, and secondary phases should be confirmed using batch-specific XRD refinement, elemental analysis, and microscopic structural characterization.

Core Product Features

In-Plane Ordered Research Systems

Suitable for studying the arrangement, occupancy, and degree of ordering of two transition metals within the M layers.

Mo/Y and Mo/Sc Combinations

Two M-site systems enable comparison of how different secondary M elements affect structure and reaction behavior.

211-Type Layered Structure

Features alternating M–C and Al layers and supports research on interlayer bonding and structural evolution.

Suitable for 2D Derivative Research

Can be used in exploratory studies of selective reactions, structural conversion, and two-dimensional layered derivative materials.

Two Mesh Options

The 200-mesh grade is suitable for sintering and solid-state experiments, while the 400-mesh grade supports dispersion, slurries, and fine mixing.

Batch Characterization Available

Batch-specific XRD, SEM, EDS, and particle-size data may be available upon request.

Typical Applications

Application AreaApplication Description
Fundamental i-MAX ResearchCrystal structure, lattice parameters, phase composition, and interlayer bonding
M-Site Ordering ResearchArrangement, occupancy, and local degree of ordering of Mo with Y or Sc in the M layers
Elemental Distribution ResearchSpatial distribution, segregation, and compositional uniformity of different M-site elements
Powder SinteringPressureless sintering, hot pressing, spark-plasma sintering, and densification experiments
Structural StabilityEffects of heat treatment, atmosphere, and temperature on crystal structure and phase composition
Selective ReactionsSelective reactions involving Al layers or specific M-site elements and the associated structural evolution
Two-Dimensional Derivative MaterialsExploratory use as precursors for two-dimensional layered carbides and related derivative structures
Composite MaterialsCombination with metals, ceramics, polymers, or carbon materials to study interfaces and reinforcement effects
Electrical and Electrochemical ResearchElectronic structure, electrical conduction, electrochemical response, and interfacial reactions
Computational and Experimental ComparisonValidation of structural predictions and first-principles calculations using experimental characterization

Mesh Size and Packaging Selection

SpecificationKey CharacteristicsRecommended Uses
200 MeshRelatively coarse particles with good flowabilitySolid-state reactions, pellet pressing, sintering, and routine composite preparation
400 MeshFiner powder with a relatively larger contact areaSlurries, coatings, fine mixing, dispersion, and selective-reaction experiments
1 gSuitable for small-quantity model screeningPreliminary characterization, material selection, reaction-condition exploration, and small-scale trials
5 gSuitable for routine trials and process screeningSintering, structural conversion, composites, and multiple-condition testing
50 gSuitable for continuous experiments and staged R&DBatch mixing, sintering, and medium-quantity research experiments
Mesh size is a sieving specification and does not represent the complete particle-size distribution. When specific D10, D50, D90, or maximum-particle-size values are required, please review the data for the relevant batch.

Instructions for Use

ProcedureInstructions
Model SelectionSelect the Mo/Y or Mo/Sc system according to the research objective, mesh size, and required quantity
Batch VerificationBefore use, verify the product label, chemical formula, mesh size, and batch-specific characterization data
Opening and SamplingUse clean, dry sampling tools and avoid moisture, oil contamination, and cross-contamination
PretreatmentFor moisture-sensitive experiments, low-temperature vacuum drying or inert-atmosphere drying may be used
Powder MixingUse mechanical stirring, low-energy ball milling, or another suitable method according to the formulation
DispersionFor slurry experiments, optimize the solvent, dispersant, stirring, and ultrasonication conditions
Pellet Pressing and SinteringSet forming pressure, sintering temperature, atmosphere, and holding time according to the research objective
Selective ReactionDetermine reaction medium, temperature, duration, and solid-to-liquid ratio through small-scale trials
Post-TreatmentAfter reaction, wash, separate, dry, or store under an inert atmosphere according to the experimental system
Result CharacterizationUse XRD, SEM, EDS, TEM, and relevant performance tests to confirm the final material condition

Product Selection Guide

Research RequirementRecommended Model or Specification
Mo/Y In-Plane Ordered System Research(Mo2/3Y1/3)2AlC
Mo/Sc In-Plane Ordered System Research(Mo2/3Sc1/3)2AlC
Comparison of Y and Sc EffectsSelect both product models
Solid-State Reactions, Pellet Pressing, and SinteringPrioritize 200 mesh
Slurries, Dispersion, and Selective ReactionsPrioritize 400 mesh
Preliminary Characterization and Condition ScreeningChoose 1 g packages
Routine Trials and Multi-Condition ReactionsChoose 5 g packages
Continuous Experiments and Staged R&DChoose 50 g packages

Recommended Characterization

Characterization MethodPrimary Purpose
XRDConfirm the primary i-MAX phase, crystal structure, lattice parameters, and possible secondary phases
XRD RefinementAnalyze lattice parameters, phase ratios, and possible elemental-occupancy information
SEMObserve particle morphology, surface condition, layered features, and agglomeration
TEM / STEMObserve local lattice, in-plane ordering, atomic arrangement, defects, and interfacial structures
EDSAnalyze the composition and spatial distribution of Mo, Y or Sc, Al, and C
XPSAnalyze surface chemical states and bonding changes before and after reaction
Particle-Size AnalysisDetermine D10, D50, D90, and the complete particle-size distribution
Thermal AnalysisStudy thermal stability, oxidation processes, and mass changes during heat treatment
Quantitative Elemental AnalysisVerify the actual Mo:Y or Mo:Sc ratio and overall stoichiometry
Electrical and Electrochemical TestingStudy electrical conduction, electrochemical response, and the performance of two-dimensional derivative materials

Storage and Safety

ItemRecommendation
Storage EnvironmentStore sealed in a cool, dry place away from direct light
Storage After OpeningReseal promptly after sampling and avoid prolonged exposure to air and moisture
Long-Term StorageVacuum or inert-gas protection may be used when required
Personal ProtectionWear laboratory gloves, a dust mask or suitable respirator, protective clothing, and safety goggles
Dust ControlAvoid generating airborne dust and operate in a fume hood or under local dust extraction
Reaction HandlingWhen acids, alkalis, or other corrosive media are involved, follow the relevant chemical-handling procedures
Cross-ContaminationUse dedicated or thoroughly cleaned sampling, grinding, and mixing tools for different models
Waste DisposalDispose of the material according to laboratory requirements for inorganic powders and metal-containing waste
Intended UseFor scientific research and industrial R&D only; not intended for food, medical, or human-use applications

Frequently Asked Questions

1. What is an i-MAX phase?
An i-MAX phase is a multi-metal MAX-phase material in which two transition-metal elements may form a specific in-plane arrangement within the M layers. Compared with conventional single-M-site MAX phases, i-MAX materials are particularly suitable for studying elemental ordering, local lattice distortion, selective reactions, and two-dimensional layered derivative structures.
2. Are Mo and Y or Sc necessarily fully ordered?
Not necessarily. The catalog formula indicates nominal composition but does not by itself prove complete M-site ordering. The actual degree of ordering should be evaluated using XRD refinement, atomic-resolution STEM, EDS, and other structural-characterization techniques.
3. What is the main difference between the two products?
(Mo₂/₃Y₁/₃)₂AlC contains Y, while (Mo₂/₃Sc₁/₃)₂AlC contains Sc. Different secondary M elements may affect lattice dimensions, local structure, elemental occupancy, thermal stability, and selective-reaction behavior. The actual differences should be determined through relevant experimental characterization.
4. How should I choose between 200 and 400 mesh?
The 200-mesh grade has relatively coarser particles and is generally suitable for solid-state reactions, pellet pressing, and sintering. The 400-mesh grade is finer and is more suitable for slurries, dispersion, fine mixing, and selective-reaction experiments. Mesh size is a sieving specification and does not represent the complete particle-size distribution.
5. Can i-MAX phases be used directly to prepare two-dimensional derivative materials?
They can be used as research precursors for two-dimensional layered derivative materials, but reaction activity, selectivity, product structure, and surface condition may vary by model. Preliminary trials should be conducted, and the reaction medium, temperature, duration, and post-treatment conditions should be optimized using XRD, SEM, TEM, and elemental-analysis results.

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Quaternary i-MAX Phase (211) Specifications / Price List

Research-Grade Powder ' Purity ≥99% ' 200 Mesh and 400 Mesh Available ' 1 g, 5 g, and 50 g Options

Product ModelMesh Size1 g5 g50 g
(Mo2/3Y1/3)2AlC200 Mesh$70$194$1,648
400 Mesh$74$193$1,642
(Mo2/3Sc1/3)2AlC200 Mesh$70$194$1,648
400 Mesh$74$193$1,642

Partial references citing our materials (from Google Scholar)


Carbon Dioxide Reduction

1. ACS Nano Strain Relaxation in Metal Alloy Catalysts Steers the Product Selectivity of Electrocatalytic CO2 Reduction

The bipolar membrane (Fumasep FBM) in this paper was purchased from SCI Materials Hub, which was used in rechargeable Zn-CO2 battery tests. The authors reported a strain relaxation strategy to determine lattice strains in bimetal MNi alloys (M = Pd, Ag, and Au) and realized an outstanding CO2-to-CO Faradaic efficiency of 96.6% with outstanding activity and durability toward a Zn-CO2 battery.


2. Front. Chem. Boosting Electrochemical Carbon Dioxide Reduction on Atomically Dispersed Nickel Catalyst

In this paper, Vulcan XC-72R was purchased from SCI Materials Hub. Vulcan XC 72R carbon is the most common catalyst support used in the anode and cathode electrodes of Polymer Electrolyte Membrane Fuel Cells (PEMFC), Direct Methanol Fuel Cells (DMFC), Alkaline Fuel Cells (AFC), Microbial Fuel Cells (MFC), Phosphoric Acid Fuel Cells (PAFC), and many more!


3. Adv. Mater. Partially Nitrided Ni Nanoclusters Achieve Energy-Efficient Electrocatalytic CO2 Reduction to CO at Ultralow Overpotential

An AEM membrane (Sustainion X37-50 Grade RT, purchased from SCI Materials Hub) was activated in 1 M KOH for 24 h, washed with ultra-purity water prior to use.


4. Adv. Funct. Mater. Nanoconfined Molecular Catalysts in Integrated Gas Diffusion Electrodes for High-Current-Density CO2 Electroreduction

In this paper (Supporting Information), an anion exchanged membrane (Fumasep FAB-PK-130 obtained from SCI Materials Hub (www.scimaterials.cn)) was used to separate the catholyte and anolyte chambers.

SCI Materials Hub: we also recommend our Fumasep FAB-PK-75 for the use in a flow cell.


5. Appl. Catal. B Efficient utilization of nickel single atoms for CO2 electroreduction by constructing 3D interconnected nitrogen-doped carbon tube network

In this paper, the Nafion 117 membrane was obtained from SCI Materials Hub.


6. Vacuum Modulable Cu(0)/Cu(I)/Cu(II) sites of Cu/C catalysts derived from MOF for highly selective CO2 electroreduction to hydrocarbons

In this paper, Proton exchange membrane (Nafion 117), Nafion D520, and Toray 060 carbon paper were purchased from SCI Materials Hub.


7. National Science Review Confinement of ionomer for electrocatalytic CO2 reduction reaction via efficient mass transfer pathways

An anion exchange membrane (PiperION-A15-HCO3) was obtained from SCI Materials Hub.


8. Catalysis Communications Facilitating CO2 electroreduction to C2H4 through facile regulating {100} & {111} grain boundary of Cu2O

Carbon paper (TGPH060), membrane solution (Nafion D520), and ionic membrane (Nafion N117) were obtained from Wuhu Eryi Material Technology Co., Ltd (a company under SCI Materials Hub).


Batteries

1. J. Mater. Chem. A Blocking polysulfides with a Janus Fe3C/N-CNF@RGO electrode via physiochemical confinement and catalytic conversion for high-performance lithium–sulfur batteries

Graphene oxide (GO) in this paper was obtained from SCI Materials Hub. The authors introduced a Janus Fe3C/N-CNF@RGO electrode consisting of 1D Fe3C decorated N-doped carbon nanofibers (Fe3C/N-CNFs) side and 2D reduced graphene oxide (RGO) side as the free-standing carrier of Li2S6 catholyte to improve the overall electrochemical performance of Li-S batteries.


2. Joule A high-voltage and stable zinc-air battery enabled by dual-hydrophobic-induced proton shuttle shielding

This paper used more than 10 kinds of materials from SCI Materials Hub and the authors gave detailed properity comparsion.

The commercial IEMs of Fumasep FAB-PK-130 and Nafion N117 were obtained from SCI Materials Hub.

Gas diffusion layers of GDL340 (CeTech) and SGL39BC (Sigracet) and Nafion dispersion (Nafion D520) were obtained from SCI Materials Hub.

Zn foil (100 mm thickness) and Zn powder were obtained from the SCI Materials Hub.

Commercial 20% Pt/C, 40% Pt/C and IrO2 catalysts were also obtained from SCI Materials Hub.


3. Journal of Energy Chemistry Vanadium oxide nanospheres encapsulated in N-doped carbon nanofibers with morphology and defect dual-engineering toward advanced aqueous zinc-ion batteries

In this paper, carbon cloth (W0S1011) was obtained from SCI Materials Hub. The flexible carbon cloth matrix guaranteed the stabilization of the electrode and improved the conductivity of the cathode.


4. Energy Storage Materials Defect-abundant commercializable 3D carbon papers for fabricating composite Li anode with high loading and long life

The 3D carbon paper (TGPH060 raw paper) were purchased from SCI Materials Hub.


5. Nanomaterials A Stable Rechargeable Aqueous Zn–Air Battery Enabled by Heterogeneous MoS2 Cathode Catalysts

Nafion D520 (5 wt%), and carbon paper (GDL340) were received from SCI-Materials-Hub.


6. SSRN An Axially Directed Cobalt-Phthalocyanine Covalent Organic Polymer as High-Efficient Bifunctional Catalyst for Zn-Air Battery

Carbon cloth (W0S1011) and other electrochemical consumables required for air cathode were provided by SCI Materials Hub.


Oxygen Reduction Reaction

1. J. Chem. Eng. Superior Efficiency Hydrogen Peroxide Production in Acidic Media through Epoxy Group Adjacent to Co-O/C Active Centers on Carbon Black

In this paper, Vulcan XC 72 carbon black, ion membrane (Nafion N115, 127 μL), Nafion solution (D520, 5 wt%), and carbon paper (AvCarb GDS 2230 and Spectracarb 2050A-1050) were purchased from SCI Materials Hub.


2. Journal of Colloid and Interface Science Gaining insight into the impact of electronic property and interface electrostatic field on ORR kinetics in alloy engineering via theoretical prognostication and experimental validation

The 20 wt% Pt3M (M = Cr, Co, Cu, Pd, Sn, and Ir) were purchased from SCI Materials Hub. This work places emphasis on the kinetics of the ORR concerning Pt3M (M = Cr, Co, Cu, Pd, Sn, and Ir) catalysts, and integrates theoretical prognostication and experimental validation to illuminate the fundamental principles of alloy engineering.


Water Electrolysis

1. International Journal of Hydrogen Energy Gold as an efficient hydrogen isotope separation catalyst in proton exchange membrane water electrolysis

The cathodic catalysts of Pt/C (20 wt%, 2–3 nm) and Au/C (20 wt%, 4–5 nm) were purchased from SCI Materials Hub.


2. Small Science Silver Compositing Boosts Water Electrolysis Activity and Durability of RuO2 in a Proton-Exchange-Membrane Water Electrolyzer

Two fiber felts (0.35 mm thickness, SCI Materials Hub) were used as the porous transport layers at both the cathode and the anode.


3. Advanced Functional Materials Hierarchical Crystalline/Amorphous Heterostructure MoNi/NiMoOx for Electrochemical Hydrogen Evolution with Industry-Level Activity and Stability

Anion-exchange membrane (FAA-3-PK-130) was obtained from SCI Materials Hub website.


Fuel Cells

1. Polymer Sub-two-micron ultrathin proton exchange membrane with reinforced mechanical strength

Gas diffusion electrode (60% Pt/C, Carbon paper) was purchased from SCI Materials Hub.


Characterization

1. Chemical Engineering Journal Electrochemical reconstitution of Prussian blue analogue for coupling furfural electro-oxidation with photo-assisted hydrogen evolution reaction

An Au nanoparticle film was deposited on the total reflecting plane of a single reflection ATR crystal (SCI Materials Hub, Wuhu, China) via sputter coater.

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