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SciMater™ High-Entropy MAX Phase Powder

  • Product Code:(Ti1/5Zr1/5V1/5Nb1/5Ta1/5)2AlC, (Ti1/5Hf1/5V1/5Nb1/5Ta1/5)2AlC, (Ti1/5V1/5Nb1/5Ta1/5Mo1/5)4AlC3
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SciMater™ HIGH-ENTROPY MAX PHASE MATERIALS

Research-Grade High-Entropy MAX Phase Powders

Five-Component Equimolar M-Site Systems | Nominal Purity ≥99% | 200, 400, and 600 Mesh Options | Standard Packaging: 1 g, 5 g, and 50 g

High-Entropy MAX Phases Five-Component M Sites Research-Grade Powder 211-Type / 413-Type 3 Product Models

This series includes (Ti1/5Zr1/5V1/5Nb1/5Ta1/5)2AlC, (Ti1/5Hf1/5V1/5Nb1/5Ta1/5)2AlC, and (Ti1/5V1/5Nb1/5Ta1/5Mo1/5)4AlC3. These materials are suitable for research on multi-component M-site solid solutions, configurational entropy, lattice distortion, elemental distribution, thermal stability, sintering, and layered derivative materials.

Product Series High-Entropy MAX
Nominal Purity ≥99%
Available Mesh Sizes 200–600 Mesh
Standard Packaging 1 g / 5 g / 50 g

Product Description

High-entropy MAX phases are multi-component layered materials formed by introducing multiple transition-metal elements into the M-site sublattice of conventional MAX phases. Each product in this series uses a nominally equimolar combination of five M-site elements, with each element accounting for one fifth of the total M-site content. These materials support studies of configurational entropy, lattice distortion, elemental synergy, and multi-component solid-solution effects on MAX-phase structure and properties.

The series includes both 211-type and 413-type structures. The 211 type is generally represented as M2AlC, while the 413 type is generally represented as M4AlC3. Catalog formulas indicate nominal composition only. Actual elemental ratios, spatial distribution, primary-phase content, lattice parameters, and secondary phases should be confirmed using batch-specific XRD, elemental-analysis, and microscopic-characterization data.

Series Specifications

ParameterSeries Information
Product SeriesHigh-Entropy MAX Phase Research-Grade Powders
Structural Types211-Type and 413-Type Layered Carbides
M-Site CompositionNominal equimolar mixture of five transition-metal elements
A-Site ElementAl
X-Site ElementC
Product FormPowder
Product GradeResearch Grade
Nominal Purity≥99%
Available Mesh Sizes200, 400, and 600 mesh
Standard Packaging1 g, 5 g, and 50 g
Primary ElementsTi, Zr, Hf, V, Nb, Ta, Mo, Al, and C
Characterization DataBatch-specific XRD, SEM, EDS, and particle-size data may be available upon request
Customization ServicesSpecial mesh sizes, packaging, bulk quantities, and characterization requirements are available upon request
Inventory and Lead TimePlease inquire before ordering

Core Information Comparison Across the Full Product Series

Product ModelStructural TypeM-Site ElementsNominal M-Site RatioA-Site ElementX-Site ElementAvailable Mesh SizesComposition FeatureRecommended Research Areas
(Ti1/5Zr1/5V1/5Nb1/5Ta1/5)2AlC211-TypeTi, Zr, V, Nb, and Ta1:1:1:1:1AlC200, 400, and 600 meshFive-component equimolar M-site system containing ZrConfigurational entropy, lattice distortion, elemental distribution, sintering, and high-temperature stability
(Ti1/5Hf1/5V1/5Nb1/5Ta1/5)2AlC211-TypeTi, Hf, V, Nb, and Ta1:1:1:1:1AlC200, 400, and 600 meshFive-component equimolar M-site system containing HfHeavy-element effects, lattice stability, high-temperature behavior, mechanical properties, and oxidation resistance
(Ti1/5V1/5Nb1/5Ta1/5Mo1/5)4AlC3413-TypeTi, V, Nb, Ta, and Mo1:1:1:1:1AlC200, 400, and 600 meshFive-component equimolar M-site system containing MoThicker M–C layers, electronic structure, thermal stability, sintering, and layered derivative materials
Catalog formulas indicate nominal equimolar composition and do not guarantee completely uniform microscopic distribution of all five elements. Actual elemental ratios, degree of solid solution, M-site occupancy, lattice parameters, primary-phase content, and secondary phases should be confirmed using batch-specific characterization data.

Core Product Features

Five-Component M-Site Design

Five transition metals nominally share the M site in equal proportions, supporting studies of multi-component synergy.

High Configurational Entropy

Suitable for analyzing how configurational entropy affects solid-solution stability, lattice structure, and phase formation.

211-Type and 413-Type Structures

Includes two layered structural types for comparison of M–C layer thickness and structural differences.

Diverse Elemental Combinations

Includes Ti, Zr, Hf, V, Nb, Ta, and Mo across the available high-entropy systems.

Multiple Mesh Options

Available in 200, 400, and 600 mesh grades for sintering, mixing, dispersion, and coating experiments.

Batch Characterization Available

Batch-specific XRD, SEM, EDS, and particle-size data may be available upon request.

Typical Applications

Application AreaApplication Description
Fundamental High-Entropy MAX ResearchPhase formation, crystal structure, lattice parameters, and configurational-entropy effects
Multi-Component Solid-Solution ResearchSolid-solution behavior, segregation, and spatial distribution of five M-site elements
Lattice-Distortion ResearchEffects of different atomic sizes and chemical characteristics on the local lattice
Powder SinteringPressureless sintering, hot pressing, spark-plasma sintering, and densification experiments
High-Temperature PerformanceThermal stability, oxidation behavior, thermal expansion, and high-temperature mechanical properties
Composite MaterialsCombination with metals, ceramics, polymers, or carbon materials to study interfaces and reinforcement effects
Functional CoatingsWear-resistant, conductive, high-temperature-resistant, and oxidation-resistant coating formulations
Electrical and Electronic StructureElectrical conduction, band structure, carrier behavior, and temperature-dependent transport
Layered Derivative MaterialsA-layer reactions, structural evolution, and multi-component two-dimensional layered materials
Computational Materials ResearchFirst-principles calculations, structural prediction, and comparison with experimental results

Mesh Size and Packaging Selection

SpecificationKey CharacteristicsRecommended Uses
200 MeshRelatively coarse particles with good flowabilitySolid-state reactions, pellet pressing, sintering, and routine composite preparation
400 MeshFiner powder with a relatively larger contact areaSlurries, coatings, dispersion, interfacial reactions, and fine mixing
600 MeshHigher fineness suitable for more uniform powder mixingFine coating, thin-layer preparation, and highly uniform formulations
1 gSuitable for small-quantity model screeningPreliminary characterization, material selection, formulation validation, and small-scale trials
5 gSuitable for routine trials and process screeningSintering, composite preparation, coatings, and multiple performance tests
50 gSuitable for continuous experiments and staged R&DBatch mixing, sintering, and medium-quantity research experiments
Mesh size is a sieving specification and does not represent the complete particle-size distribution. When specific D10, D50, D90, maximum-particle-size, or specific-surface-area values are required, please review the data for the relevant batch.

Instructions for Use

ProcedureInstructions
Model SelectionSelect the product according to the 211- or 413-type structure, M-site combination, mesh size, and research objective
Batch VerificationBefore use, verify the product label, chemical formula, mesh size, and batch-specific characterization data
Opening and SamplingUse clean, dry sampling tools and avoid moisture, oil contamination, and cross-contamination
PretreatmentFor moisture-sensitive experiments, low-temperature vacuum drying or inert-atmosphere drying may be used
Powder MixingUse mechanical stirring, low-energy ball milling, or another suitable method according to the formulation
DispersionFor slurry experiments, optimize the solvent, dispersant, stirring, and ultrasonication conditions
Pellet FormingPellet pressing may be performed before sintering; adjust pressure according to the equipment and powder condition
Heat TreatmentDetermine sintering temperature, atmosphere, heating rate, and holding time through preliminary trials
Structural ConversionWhen selective reactions are involved, conduct small-scale condition screening and control the reaction process
Result CharacterizationUse XRD, SEM, EDS, TEM, and relevant performance tests to confirm the final material condition

Product Selection Guide

Research RequirementRecommended Model or Specification
Zr-Containing Five-Component 211-Type System(Ti1/5Zr1/5V1/5Nb1/5Ta1/5)2AlC
Hf-Containing Five-Component 211-Type System(Ti1/5Hf1/5V1/5Nb1/5Ta1/5)2AlC
Mo-Containing Five-Component 413-Type System(Ti1/5V1/5Nb1/5Ta1/5Mo1/5)4AlC3
Comparison of Zr and Hf EffectsSelect both 211-type products
Comparison of 211-Type and 413-Type StructuresSelect at least one 211-type and one 413-type product
Pellet Pressing, Sintering, and Solid-State ReactionsPrioritize 200 mesh
Slurries, Coatings, and Fine DispersionPrioritize 400 or 600 mesh
Preliminary Characterization and Model ScreeningChoose 1 g packages
Routine Trials and Multi-Group ExperimentsChoose 5 g packages
Continuous Experiments and Staged R&DChoose 50 g packages

Recommended Characterization

Characterization MethodPrimary Purpose
XRDConfirm the primary MAX phase, crystal structure, lattice parameters, and possible secondary phases
XRD RefinementAnalyze lattice parameters, phase ratios, and structural changes caused by multi-component solid solutions
SEMObserve particle morphology, surface condition, layered features, and agglomeration
TEM / STEMObserve local lattice, defects, interfaces, and distribution characteristics of different M-site elements
EDS MappingAnalyze spatial distribution and uniformity of the five M-site elements
Quantitative Elemental AnalysisVerify the actual ratio of each M-site element and the overall stoichiometry
XPSAnalyze surface chemical states and bonding information among multiple elements
Particle-Size AnalysisDetermine D10, D50, D90, and the complete particle-size distribution
Thermal AnalysisStudy thermal stability, oxidation processes, and mass changes with temperature
Electrical and Mechanical TestingStudy electrical conduction, hardness, indentation, fracture, and high-temperature mechanical properties

Storage and Safety

ItemRecommendation
Storage EnvironmentStore sealed in a cool, dry place away from direct light
Storage After OpeningReseal promptly after sampling and avoid prolonged exposure to air and moisture
Long-Term StorageVacuum or inert-gas protection may be used when required
Personal ProtectionWear laboratory gloves, a dust mask or suitable respirator, protective clothing, and safety goggles
Dust ControlAvoid generating airborne dust and operate in a fume hood or under local dust extraction
Cross-ContaminationUse dedicated or thoroughly cleaned sampling, grinding, and mixing tools for different product models
Waste DisposalDispose of the material according to laboratory requirements for inorganic powders and metal-containing waste
Intended UseFor scientific research and industrial R&D only; not intended for food, medical, or human-use applications

Frequently Asked Questions

1. What is a high-entropy MAX phase?
A high-entropy MAX phase is a multi-component layered material formed by introducing multiple transition-metal elements into the M-site sublattice of a MAX phase. This series uses nominally equimolar combinations of five M-site elements and is suitable for research on configurational entropy, lattice distortion, elemental synergy, and multi-component solid-solution effects.
2. Are the five M-site elements necessarily distributed completely uniformly?
Not necessarily. The chemical formula indicates nominal feed composition and target stoichiometry but does not by itself prove complete microscopic uniformity. Actual elemental distribution should be evaluated using EDS mapping, TEM/STEM, quantitative elemental analysis, and other structural-characterization techniques.
3. What is the difference between 211-type and 413-type high-entropy MAX phases?
The 211 type is generally represented as M₂AlC, while the 413 type is generally represented as M₄AlC₃. The two structures differ in M–C layer thickness and crystal architecture and may exhibit different thermal stability, electronic structure, mechanical behavior, and selective-reaction characteristics.
4. How should I choose among 200, 400, and 600 mesh?
The 200-mesh grade is generally suitable for solid-state reactions, pellet pressing, and sintering. The 400-mesh grade is suitable for slurries, coatings, and fine mixing. The 600-mesh grade is suitable for dispersion and thin-layer preparation requiring greater fineness and mixing uniformity. Mesh size is a sieving specification and does not represent the complete particle-size distribution.
5. Does nominal purity ≥99% mean that the primary high-entropy MAX-phase content is also ≥99%?
Not necessarily. Chemical purity and phase purity are different specifications. When strict requirements apply to primary MAX-phase content, secondary phases, the ratio of the five M-site elements, or solid-solution uniformity, review batch-specific XRD, elemental-analysis, SEM, EDS, and other characterization data.

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High-Entropy MAX Phase Specifications / Price List

Research-Grade Powder ' Purity ≥99% ' 200, 400, and 600 Mesh Available ' 1 g, 5 g, and 50 g Options

Product ModelMesh Size1 g5 g50 g
(Ti1/5Zr1/5V1/5Nb1/5Ta1/5)2AlC200 Mesh$60$253$2,153
400 Mesh$63$255$2,168
600 Mesh$67$270$2,295
(Ti1/5Hf1/5V1/5Nb1/5Ta1/5)2AlC200 Mesh$60$253$2,153
400 Mesh$63$255$2,168
600 Mesh$67$270$2,295
(Ti1/5V1/5Nb1/5Ta1/5Mo1/5)4AlC3200 Mesh$60$253$2,153
400 Mesh$63$255$2,168
600 Mesh$67$270$2,295

Partial references citing our materials (from Google Scholar)


Carbon Dioxide Reduction

1. ACS Nano Strain Relaxation in Metal Alloy Catalysts Steers the Product Selectivity of Electrocatalytic CO2 Reduction

The bipolar membrane (Fumasep FBM) in this paper was purchased from SCI Materials Hub, which was used in rechargeable Zn-CO2 battery tests. The authors reported a strain relaxation strategy to determine lattice strains in bimetal MNi alloys (M = Pd, Ag, and Au) and realized an outstanding CO2-to-CO Faradaic efficiency of 96.6% with outstanding activity and durability toward a Zn-CO2 battery.


2. Front. Chem. Boosting Electrochemical Carbon Dioxide Reduction on Atomically Dispersed Nickel Catalyst

In this paper, Vulcan XC-72R was purchased from SCI Materials Hub. Vulcan XC 72R carbon is the most common catalyst support used in the anode and cathode electrodes of Polymer Electrolyte Membrane Fuel Cells (PEMFC), Direct Methanol Fuel Cells (DMFC), Alkaline Fuel Cells (AFC), Microbial Fuel Cells (MFC), Phosphoric Acid Fuel Cells (PAFC), and many more!


3. Adv. Mater. Partially Nitrided Ni Nanoclusters Achieve Energy-Efficient Electrocatalytic CO2 Reduction to CO at Ultralow Overpotential

An AEM membrane (Sustainion X37-50 Grade RT, purchased from SCI Materials Hub) was activated in 1 M KOH for 24 h, washed with ultra-purity water prior to use.


4. Adv. Funct. Mater. Nanoconfined Molecular Catalysts in Integrated Gas Diffusion Electrodes for High-Current-Density CO2 Electroreduction

In this paper (Supporting Information), an anion exchanged membrane (Fumasep FAB-PK-130 obtained from SCI Materials Hub (www.scimaterials.cn)) was used to separate the catholyte and anolyte chambers.

SCI Materials Hub: we also recommend our Fumasep FAB-PK-75 for the use in a flow cell.


5. Appl. Catal. B Efficient utilization of nickel single atoms for CO2 electroreduction by constructing 3D interconnected nitrogen-doped carbon tube network

In this paper, the Nafion 117 membrane was obtained from SCI Materials Hub.


6. Vacuum Modulable Cu(0)/Cu(I)/Cu(II) sites of Cu/C catalysts derived from MOF for highly selective CO2 electroreduction to hydrocarbons

In this paper, Proton exchange membrane (Nafion 117), Nafion D520, and Toray 060 carbon paper were purchased from SCI Materials Hub.


7. National Science Review Confinement of ionomer for electrocatalytic CO2 reduction reaction via efficient mass transfer pathways

An anion exchange membrane (PiperION-A15-HCO3) was obtained from SCI Materials Hub.


8. Catalysis Communications Facilitating CO2 electroreduction to C2H4 through facile regulating {100} & {111} grain boundary of Cu2O

Carbon paper (TGPH060), membrane solution (Nafion D520), and ionic membrane (Nafion N117) were obtained from Wuhu Eryi Material Technology Co., Ltd (a company under SCI Materials Hub).


Batteries

1. J. Mater. Chem. A Blocking polysulfides with a Janus Fe3C/N-CNF@RGO electrode via physiochemical confinement and catalytic conversion for high-performance lithium–sulfur batteries

Graphene oxide (GO) in this paper was obtained from SCI Materials Hub. The authors introduced a Janus Fe3C/N-CNF@RGO electrode consisting of 1D Fe3C decorated N-doped carbon nanofibers (Fe3C/N-CNFs) side and 2D reduced graphene oxide (RGO) side as the free-standing carrier of Li2S6 catholyte to improve the overall electrochemical performance of Li-S batteries.


2. Joule A high-voltage and stable zinc-air battery enabled by dual-hydrophobic-induced proton shuttle shielding

This paper used more than 10 kinds of materials from SCI Materials Hub and the authors gave detailed properity comparsion.

The commercial IEMs of Fumasep FAB-PK-130 and Nafion N117 were obtained from SCI Materials Hub.

Gas diffusion layers of GDL340 (CeTech) and SGL39BC (Sigracet) and Nafion dispersion (Nafion D520) were obtained from SCI Materials Hub.

Zn foil (100 mm thickness) and Zn powder were obtained from the SCI Materials Hub.

Commercial 20% Pt/C, 40% Pt/C and IrO2 catalysts were also obtained from SCI Materials Hub.


3. Journal of Energy Chemistry Vanadium oxide nanospheres encapsulated in N-doped carbon nanofibers with morphology and defect dual-engineering toward advanced aqueous zinc-ion batteries

In this paper, carbon cloth (W0S1011) was obtained from SCI Materials Hub. The flexible carbon cloth matrix guaranteed the stabilization of the electrode and improved the conductivity of the cathode.


4. Energy Storage Materials Defect-abundant commercializable 3D carbon papers for fabricating composite Li anode with high loading and long life

The 3D carbon paper (TGPH060 raw paper) were purchased from SCI Materials Hub.


5. Nanomaterials A Stable Rechargeable Aqueous Zn–Air Battery Enabled by Heterogeneous MoS2 Cathode Catalysts

Nafion D520 (5 wt%), and carbon paper (GDL340) were received from SCI-Materials-Hub.


6. SSRN An Axially Directed Cobalt-Phthalocyanine Covalent Organic Polymer as High-Efficient Bifunctional Catalyst for Zn-Air Battery

Carbon cloth (W0S1011) and other electrochemical consumables required for air cathode were provided by SCI Materials Hub.


Oxygen Reduction Reaction

1. J. Chem. Eng. Superior Efficiency Hydrogen Peroxide Production in Acidic Media through Epoxy Group Adjacent to Co-O/C Active Centers on Carbon Black

In this paper, Vulcan XC 72 carbon black, ion membrane (Nafion N115, 127 μL), Nafion solution (D520, 5 wt%), and carbon paper (AvCarb GDS 2230 and Spectracarb 2050A-1050) were purchased from SCI Materials Hub.


2. Journal of Colloid and Interface Science Gaining insight into the impact of electronic property and interface electrostatic field on ORR kinetics in alloy engineering via theoretical prognostication and experimental validation

The 20 wt% Pt3M (M = Cr, Co, Cu, Pd, Sn, and Ir) were purchased from SCI Materials Hub. This work places emphasis on the kinetics of the ORR concerning Pt3M (M = Cr, Co, Cu, Pd, Sn, and Ir) catalysts, and integrates theoretical prognostication and experimental validation to illuminate the fundamental principles of alloy engineering.


Water Electrolysis

1. International Journal of Hydrogen Energy Gold as an efficient hydrogen isotope separation catalyst in proton exchange membrane water electrolysis

The cathodic catalysts of Pt/C (20 wt%, 2–3 nm) and Au/C (20 wt%, 4–5 nm) were purchased from SCI Materials Hub.


2. Small Science Silver Compositing Boosts Water Electrolysis Activity and Durability of RuO2 in a Proton-Exchange-Membrane Water Electrolyzer

Two fiber felts (0.35 mm thickness, SCI Materials Hub) were used as the porous transport layers at both the cathode and the anode.


3. Advanced Functional Materials Hierarchical Crystalline/Amorphous Heterostructure MoNi/NiMoOx for Electrochemical Hydrogen Evolution with Industry-Level Activity and Stability

Anion-exchange membrane (FAA-3-PK-130) was obtained from SCI Materials Hub website.


Fuel Cells

1. Polymer Sub-two-micron ultrathin proton exchange membrane with reinforced mechanical strength

Gas diffusion electrode (60% Pt/C, Carbon paper) was purchased from SCI Materials Hub.


Characterization

1. Chemical Engineering Journal Electrochemical reconstitution of Prussian blue analogue for coupling furfural electro-oxidation with photo-assisted hydrogen evolution reaction

An Au nanoparticle film was deposited on the total reflecting plane of a single reflection ATR crystal (SCI Materials Hub, Wuhu, China) via sputter coater.

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