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SciMater™ Low-Entropy MAX Phase Powder, Mo4AlC4, Mo4VAlC4

  • Product Code:Mo4AlC4, Mo4VAlC4
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SciMater™ LOW-ENTROPY MAX PHASE MATERIALS

Research-Grade Low-Entropy MAX Phase Powders

Mo-Based Layered Carbide Systems | Nominal Purity ≥99% | 200–500 Mesh Options | Standard Packaging: 1 g, 5 g, and 50 g

Low-Entropy MAX Phases Mo-Based Systems Research-Grade Powder Single-M / Dual-M Systems 2 Product Models

This series includes Mo4AlC4 and Mo4VAlC4. These materials are suitable for research on the crystal structure of Mo-based layered carbides, elemental substitution, lattice variation, phase formation, powder sintering, electronic structure, high-temperature stability, and composite materials.

Product Series Low-Entropy MAX
Nominal Purity ≥99%
Available Mesh Sizes 200–500 Mesh
Standard Packaging 1 g / 5 g / 50 g

Product Description

Low-entropy MAX-phase powders are layered carbide research materials whose M-site systems contain one or only a small number of transition-metal elements. Compared with multi-component medium- and high-entropy systems, their elemental compositions are more concentrated, making them suitable for studying dominant single-element effects, limited elemental substitution, lattice variation, and phase stability.

This series includes the catalog models Mo4AlC4 and V-containing Mo4VAlC4. Because their nominal stoichiometries differ from the common Mn+1AXnnotation, their precise crystal structures, elemental occupancy, primary-phase content, and secondary phases should be confirmed using batch-specific XRD, elemental analysis, and microscopic structural characterization.

Series Specifications

ParameterSeries Information
Product SeriesLow-Entropy MAX Phase Research-Grade Powders
Catalog ModelsMo4AlC4 and Mo4VAlC4
Material TypeMo-Based and Mo/V-Based Layered Carbide Research Materials
Primary M-Site ElementsMo; or Mo and V
A-Site ElementAl
X-Site ElementC
Product FormPowder
Product GradeResearch Grade
Nominal Purity≥99%
Available Mesh Sizes200, 300, 400, and 500 mesh, depending on the product model
Standard Packaging1 g, 5 g, and 50 g
Characterization DataBatch-specific XRD, SEM, EDS, and particle-size data may be available upon request
Customization ServicesSpecial mesh sizes, packaging, bulk quantities, and characterization requirements are available upon request
Inventory and Lead TimePlease inquire before ordering

Core Information Comparison Across the Full Product Series

Product ModelMaterial SystemM-Site ElementsA-Site ElementX-Site ElementComposition FeatureAvailable Mesh SizesRecommended Research Areas
Mo4AlC4Mo-Based Aluminum CarbideMoAlCSingle-transition-metal catalog system200, 300, 400, and 500 meshCrystal structure, phase formation, Mo-based layered carbides, sintering, and high-temperature stability
Mo4VAlC4Mo/V-Based Aluminum CarbideMo and VAlCLow-entropy multi-metal catalog system containing V200 and 400 meshV substitution, elemental occupancy, lattice variation, electronic structure, and phase stability
Mo₄AlC₄ and Mo₄VAlC₄ are displayed according to the supplied catalog formulas. Their exact crystal structures, standard structural assignment, elemental occupancy, primary-phase content, and actual stoichiometry should be confirmed using batch-specific XRD, quantitative elemental analysis, and microscopic structural characterization.

Core Product Features

Mo-Based Material Systems

Mo is the principal transition-metal component, supporting research on Mo-based layered carbides.

Low Elemental Complexity

The concentrated elemental composition facilitates analysis of single-element effects and limited substitution.

Single-M and Dual-M Comparison

Enables comparison between Mo-based and Mo/V-based systems in terms of structure, phase composition, and properties.

Multiple Mesh Options

Available in 200–500 mesh grades for sintering, mixing, dispersion, and coating experiments.

Compatible with Multiple Processing Routes

Suitable for powder mixing, pellet pressing, heat treatment, sintering, slurries, and composite preparation.

Batch Characterization Available

Batch-specific XRD, SEM, EDS, and particle-size data may be available upon request.

Typical Applications

Application AreaApplication Description
Crystal-Structure ResearchCrystal structure, lattice parameters, interlayer bonding, and local structural analysis
Phase-Formation ResearchPrimary-phase formation, secondary phases, and structural evolution under different heat-treatment conditions
Element-Substitution ResearchComparison of structural and property changes before and after introducing V into the Mo-based system
Elemental-Occupancy ResearchActual Mo/V ratio, spatial distribution, and possible occupancy characteristics
Powder SinteringPressureless sintering, hot pressing, spark-plasma sintering, and densification experiments
High-Temperature PerformanceThermal stability, oxidation behavior, thermal expansion, and high-temperature structural changes
Electrical ResearchElectrical resistivity, conduction behavior, electronic structure, and temperature-dependent transport
Composite MaterialsCombination with metals, ceramics, polymers, or carbon materials to study interfaces and reinforcement effects
Functional CoatingsConductive, wear-resistant, high-temperature-resistant, and oxidation-resistant coating formulations
Computational Materials ResearchStructural prediction, first-principles calculations, and comparison with experimental results

Mesh Size and Packaging Selection

SpecificationKey CharacteristicsRecommended Uses
200 MeshRelatively coarse particles with good flowabilitySolid-state reactions, pellet pressing, sintering, and routine composite preparation
300 MeshBalances flowability and mixing uniformityPowder mixing, formulation screening, and routine material experiments
400 MeshFiner powder with a relatively larger contact areaSlurries, coatings, dispersion, interfacial reactions, and fine mixing
500 MeshHigher fineness suitable for fine processingFine coating, thin-layer preparation, and highly uniform formulations
1 gSuitable for small-quantity model screeningPreliminary characterization, material selection, formulation validation, and small-scale trials
5 gSuitable for routine trials and process screeningSintering, composite preparation, coatings, and multiple performance tests
50 gSuitable for continuous experiments and staged R&DBatch mixing, sintering, and medium-quantity research experiments
Mesh size is a sieving specification and does not represent the complete particle-size distribution. When specific D10, D50, D90, maximum-particle-size, or specific-surface-area values are required, please review the data for the relevant batch.

Instructions for Use

ProcedureInstructions
Model SelectionSelect the Mo-based or Mo/V-based system according to mesh size, research objective, and required quantity
Batch VerificationBefore use, verify the product label, chemical formula, mesh size, and batch-specific characterization data
Opening and SamplingUse clean, dry sampling tools and avoid moisture, oil contamination, and cross-contamination
Powder PretreatmentFor moisture-sensitive experiments, low-temperature vacuum drying or inert-atmosphere drying may be used
Powder MixingUse mechanical stirring, low-energy ball milling, or another suitable method according to the formulation
DispersionFor slurry experiments, optimize the solvent, dispersant, stirring, and ultrasonication conditions
Pellet FormingPellet pressing may be performed before sintering; adjust pressure according to the equipment and powder condition
Heat TreatmentDetermine sintering temperature, atmosphere, heating rate, and holding time through preliminary trials
Sample PreparationPrepare bulk samples, composites, slurries, or functional coatings according to the research objective
Result CharacterizationUse XRD, SEM, EDS, TEM, and relevant performance tests to confirm the final material condition

Product Selection Guide

Research RequirementRecommended Model or Specification
Layered Carbide Research Dominated by a Single Mo ElementMo4AlC4
Mo/V Dual-Transition-Metal System ResearchMo4VAlC4
Comparison Before and After V IntroductionSelect both product models
Solid-State Reactions, Pellet Pressing, and SinteringPrioritize 200 or 300 mesh
Slurries, Coatings, and Fine DispersionPrioritize 400 or 500 mesh
Preliminary Characterization and Model ScreeningChoose 1 g packages
Routine Trials and Multi-Group ExperimentsChoose 5 g packages
Continuous Experiments and Staged R&DChoose 50 g packages

Recommended Characterization

Characterization MethodPrimary Purpose
XRDConfirm crystal structure, primary phase, lattice parameters, and possible secondary phases
XRD RefinementAnalyze lattice parameters, phase ratios, and structural changes after elemental introduction
SEMObserve particle morphology, surface condition, layered features, and agglomeration
TEM / STEMObserve local lattice, defects, interfaces, interlayer structures, and elemental occupancy
EDS MappingAnalyze spatial distribution and uniformity of Mo, V, Al, and C
Quantitative Elemental AnalysisVerify actual elemental ratios and overall stoichiometry
XPSAnalyze surface chemical states and bonding information among different elements
Particle-Size AnalysisDetermine D10, D50, D90, and the complete particle-size distribution
Thermal AnalysisStudy thermal stability, oxidation processes, and mass changes with temperature
Electrical and Mechanical TestingStudy electrical conduction, hardness, indentation, fracture, and high-temperature mechanical properties

Storage and Safety

ItemRecommendation
Storage EnvironmentStore sealed in a cool, dry place away from direct light
Storage After OpeningReseal promptly after sampling and avoid prolonged exposure to air and moisture
Long-Term StorageVacuum or inert-gas protection may be used when required
Personal ProtectionWear laboratory gloves, a dust mask or suitable respirator, protective clothing, and safety goggles
Dust ControlAvoid generating airborne dust and operate in a fume hood or under local dust extraction
Cross-ContaminationUse dedicated or thoroughly cleaned sampling, grinding, and mixing tools for different product models
Waste DisposalDispose of the material according to laboratory requirements for inorganic powders and metal-containing waste
Intended UseFor scientific research and industrial R&D only; not intended for food, medical, or human-use applications

Frequently Asked Questions

1. What is a low-entropy MAX phase?
A low-entropy MAX phase generally refers to a layered carbide or nitride system containing a relatively small number of M-site elements and therefore lower configurational complexity. This series is primarily Mo-based and includes a V-containing catalog composition, making it suitable for studying dominant single-element effects and limited substitution.
2. Which standard MAX structure do Mo₄AlC₄ and Mo₄VAlC₄ belong to?
The two products are displayed according to the supplied catalog formulas, whose stoichiometries differ from the standard notation commonly used for 211-, 312-, or 413-type MAX phases. Their exact structural type, crystal symmetry, and phase assignment should be determined using batch-specific XRD, structural refinement, and microscopic characterization.
3. How is V distributed in Mo₄VAlC₄?
The catalog formula alone cannot determine the precise V occupancy, degree of uniformity, or ordering pattern. Actual distribution should be evaluated using EDS mapping, TEM/STEM, quantitative elemental analysis, and other structural-characterization techniques.
4. How should I choose among 200, 300, 400, and 500 mesh?
The 200- and 300-mesh grades are generally suitable for solid-state reactions, pellet pressing, and sintering. The 400-mesh grade is suitable for slurries, coatings, and fine mixing. The 500-mesh grade is suitable for dispersion and thin-layer preparation requiring greater fineness and mixing uniformity. Mesh size is a sieving specification and does not represent the complete particle-size distribution.
5. Does nominal purity ≥99% mean that the target primary-phase content is also ≥99%?
Not necessarily. Chemical purity and phase purity are different specifications. When strict requirements apply to target-phase content, secondary phases, elemental ratios, or actual stoichiometry, review batch-specific XRD, elemental-analysis, SEM, EDS, and other characterization data.

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Low-Entropy MAX Phase Powder Specifications / Price List

Research-Grade Powder ' Purity ≥99% ' 200–500 Mesh Available ' 1 g, 5 g, and 50 g Options

Product ModelMesh Size1 g5 g50 g
Mo4AlC4200 Mesh$67$300$2,550
300 Mesh$67$303$2,576
400 Mesh$68$306$2,601
500 Mesh$69$309$2,627
Mo4VAlC4200 Mesh$70$194$1,648
400 Mesh$74$193$1,642

Partial references citing our materials (from Google Scholar)


Carbon Dioxide Reduction

1. ACS Nano Strain Relaxation in Metal Alloy Catalysts Steers the Product Selectivity of Electrocatalytic CO2 Reduction

The bipolar membrane (Fumasep FBM) in this paper was purchased from SCI Materials Hub, which was used in rechargeable Zn-CO2 battery tests. The authors reported a strain relaxation strategy to determine lattice strains in bimetal MNi alloys (M = Pd, Ag, and Au) and realized an outstanding CO2-to-CO Faradaic efficiency of 96.6% with outstanding activity and durability toward a Zn-CO2 battery.


2. Front. Chem. Boosting Electrochemical Carbon Dioxide Reduction on Atomically Dispersed Nickel Catalyst

In this paper, Vulcan XC-72R was purchased from SCI Materials Hub. Vulcan XC 72R carbon is the most common catalyst support used in the anode and cathode electrodes of Polymer Electrolyte Membrane Fuel Cells (PEMFC), Direct Methanol Fuel Cells (DMFC), Alkaline Fuel Cells (AFC), Microbial Fuel Cells (MFC), Phosphoric Acid Fuel Cells (PAFC), and many more!


3. Adv. Mater. Partially Nitrided Ni Nanoclusters Achieve Energy-Efficient Electrocatalytic CO2 Reduction to CO at Ultralow Overpotential

An AEM membrane (Sustainion X37-50 Grade RT, purchased from SCI Materials Hub) was activated in 1 M KOH for 24 h, washed with ultra-purity water prior to use.


4. Adv. Funct. Mater. Nanoconfined Molecular Catalysts in Integrated Gas Diffusion Electrodes for High-Current-Density CO2 Electroreduction

In this paper (Supporting Information), an anion exchanged membrane (Fumasep FAB-PK-130 obtained from SCI Materials Hub (www.scimaterials.cn)) was used to separate the catholyte and anolyte chambers.

SCI Materials Hub: we also recommend our Fumasep FAB-PK-75 for the use in a flow cell.


5. Appl. Catal. B Efficient utilization of nickel single atoms for CO2 electroreduction by constructing 3D interconnected nitrogen-doped carbon tube network

In this paper, the Nafion 117 membrane was obtained from SCI Materials Hub.


6. Vacuum Modulable Cu(0)/Cu(I)/Cu(II) sites of Cu/C catalysts derived from MOF for highly selective CO2 electroreduction to hydrocarbons

In this paper, Proton exchange membrane (Nafion 117), Nafion D520, and Toray 060 carbon paper were purchased from SCI Materials Hub.


7. National Science Review Confinement of ionomer for electrocatalytic CO2 reduction reaction via efficient mass transfer pathways

An anion exchange membrane (PiperION-A15-HCO3) was obtained from SCI Materials Hub.


8. Catalysis Communications Facilitating CO2 electroreduction to C2H4 through facile regulating {100} & {111} grain boundary of Cu2O

Carbon paper (TGPH060), membrane solution (Nafion D520), and ionic membrane (Nafion N117) were obtained from Wuhu Eryi Material Technology Co., Ltd (a company under SCI Materials Hub).


Batteries

1. J. Mater. Chem. A Blocking polysulfides with a Janus Fe3C/N-CNF@RGO electrode via physiochemical confinement and catalytic conversion for high-performance lithium–sulfur batteries

Graphene oxide (GO) in this paper was obtained from SCI Materials Hub. The authors introduced a Janus Fe3C/N-CNF@RGO electrode consisting of 1D Fe3C decorated N-doped carbon nanofibers (Fe3C/N-CNFs) side and 2D reduced graphene oxide (RGO) side as the free-standing carrier of Li2S6 catholyte to improve the overall electrochemical performance of Li-S batteries.


2. Joule A high-voltage and stable zinc-air battery enabled by dual-hydrophobic-induced proton shuttle shielding

This paper used more than 10 kinds of materials from SCI Materials Hub and the authors gave detailed properity comparsion.

The commercial IEMs of Fumasep FAB-PK-130 and Nafion N117 were obtained from SCI Materials Hub.

Gas diffusion layers of GDL340 (CeTech) and SGL39BC (Sigracet) and Nafion dispersion (Nafion D520) were obtained from SCI Materials Hub.

Zn foil (100 mm thickness) and Zn powder were obtained from the SCI Materials Hub.

Commercial 20% Pt/C, 40% Pt/C and IrO2 catalysts were also obtained from SCI Materials Hub.


3. Journal of Energy Chemistry Vanadium oxide nanospheres encapsulated in N-doped carbon nanofibers with morphology and defect dual-engineering toward advanced aqueous zinc-ion batteries

In this paper, carbon cloth (W0S1011) was obtained from SCI Materials Hub. The flexible carbon cloth matrix guaranteed the stabilization of the electrode and improved the conductivity of the cathode.


4. Energy Storage Materials Defect-abundant commercializable 3D carbon papers for fabricating composite Li anode with high loading and long life

The 3D carbon paper (TGPH060 raw paper) were purchased from SCI Materials Hub.


5. Nanomaterials A Stable Rechargeable Aqueous Zn–Air Battery Enabled by Heterogeneous MoS2 Cathode Catalysts

Nafion D520 (5 wt%), and carbon paper (GDL340) were received from SCI-Materials-Hub.


6. SSRN An Axially Directed Cobalt-Phthalocyanine Covalent Organic Polymer as High-Efficient Bifunctional Catalyst for Zn-Air Battery

Carbon cloth (W0S1011) and other electrochemical consumables required for air cathode were provided by SCI Materials Hub.


Oxygen Reduction Reaction

1. J. Chem. Eng. Superior Efficiency Hydrogen Peroxide Production in Acidic Media through Epoxy Group Adjacent to Co-O/C Active Centers on Carbon Black

In this paper, Vulcan XC 72 carbon black, ion membrane (Nafion N115, 127 μL), Nafion solution (D520, 5 wt%), and carbon paper (AvCarb GDS 2230 and Spectracarb 2050A-1050) were purchased from SCI Materials Hub.


2. Journal of Colloid and Interface Science Gaining insight into the impact of electronic property and interface electrostatic field on ORR kinetics in alloy engineering via theoretical prognostication and experimental validation

The 20 wt% Pt3M (M = Cr, Co, Cu, Pd, Sn, and Ir) were purchased from SCI Materials Hub. This work places emphasis on the kinetics of the ORR concerning Pt3M (M = Cr, Co, Cu, Pd, Sn, and Ir) catalysts, and integrates theoretical prognostication and experimental validation to illuminate the fundamental principles of alloy engineering.


Water Electrolysis

1. International Journal of Hydrogen Energy Gold as an efficient hydrogen isotope separation catalyst in proton exchange membrane water electrolysis

The cathodic catalysts of Pt/C (20 wt%, 2–3 nm) and Au/C (20 wt%, 4–5 nm) were purchased from SCI Materials Hub.


2. Small Science Silver Compositing Boosts Water Electrolysis Activity and Durability of RuO2 in a Proton-Exchange-Membrane Water Electrolyzer

Two fiber felts (0.35 mm thickness, SCI Materials Hub) were used as the porous transport layers at both the cathode and the anode.


3. Advanced Functional Materials Hierarchical Crystalline/Amorphous Heterostructure MoNi/NiMoOx for Electrochemical Hydrogen Evolution with Industry-Level Activity and Stability

Anion-exchange membrane (FAA-3-PK-130) was obtained from SCI Materials Hub website.


Fuel Cells

1. Polymer Sub-two-micron ultrathin proton exchange membrane with reinforced mechanical strength

Gas diffusion electrode (60% Pt/C, Carbon paper) was purchased from SCI Materials Hub.


Characterization

1. Chemical Engineering Journal Electrochemical reconstitution of Prussian blue analogue for coupling furfural electro-oxidation with photo-assisted hydrogen evolution reaction

An Au nanoparticle film was deposited on the total reflecting plane of a single reflection ATR crystal (SCI Materials Hub, Wuhu, China) via sputter coater.

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