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Sigracet 22 BB

  • Product Code:212202
  • Description:Sigracet 22 BB
  • Brand:SGL Carbon
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  • Keywords:Sigracet 22 BB, SCI Materials Hub
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1. Introduction

Sigracet 22 BB is a non-woven carbon paper with a Microporous Layer (MPL) that has been PTFE treated to 5 wt%. It has a total thickness of 215 um (microns). The hydrophobic treatment produces water repellent properties which prevent the highly porous carbon fiber backings from flooding and actively support the water management of PEM fuel cells. SGL BB is a great low-cost alternative to conventional woven carbon paper Gas Diffusion Layer (GDL) and Gas Diffusion Media materials.


2. Features

The Sigracet Carbon Fiber Paper 22 Series is intended to combine the required production robustness and the excellent performance properties. Stack developers and assemblers are benefiting from the following greatly improved characteristics:

- Greatly improved homogeneity inter-lot and intra-lot. The overall variability has been shown to be better than +/- 10% (2 sigma)
- Greatly improved surface flatness
- Greatly reduced occurrence of faulty spots on a roll

- Best performance under various operating conditions

- Recommended Applications: PEMFC automotive, PEM electrolysis

Sigracet 29 BC was discontinued and permanently replaced by Sigracet 22 BB.


3. Sigracet GDL series in SCI Materials Hub

SeriesSigracet 22BBSigracet 28BCSigracet 29BCSigracet 35BCSigracet 36BBSigracet 39BB
Thickness0.215 mm0.235 mm0.235 mm0.325 mm0.280 mm0.315 mm


4. Welcome to cite our materials in your papers

1. Gas diffusion layer Sigracet 22BB was obtained from SCI Materials Hub.

2. Commercially available Sigracet 22BB gas diffusion layers (GDLs, SCI Materials Hub) comprised of 5 wt% PTFE-treated carbon paper and a teflonized microporous layer, were used.

Download:

Sigracet 22 BB Carbon Paper Property Sheet.pdf

Sigracet GDL Handling Instructions.pdf


Gas Diffusion Layer Properties
Material TypeCarbon Fiber Paper
Thickness215 microns +/- 20 microns
Areal Weight70 +/- 15 g/m2
Electrical Resistivity< 10 mΩcm2 (milli-ohms cm2)
Thermal Conductivity0.30 W(m-1)(K-1)
Bending Stiffness (MD/TD)1.5 / 0.9 N mm
Gas Permeability1.2 Gurley sec
Compressibility20% (@ 5psi, 1 MPa)
Water Contact Angle (MPL)> 130°
Roughness (MPL side)7.2 μm
Impurities (Fe, Co, Ni)< 10 ppm
Tensile Strength6.9 / 4.6 MPa (MD/TD)
PTFE Treatment5%
Microporous LayerYes, on one side

SGL Carbon develops and commercializes carbon-based products for Polymer-Electrolyte-Membrane Fuel Cells (PEFC):

- Gas Diffusion Layers (GDL)

- Foils used as separator plates for fuel cells and redox-flow batteries (Expanded Graphite)


GDLs are typically designed as a bilayer structure consisting of a macro-porous backing material (carbon fiber paper support) and a micro-porous, carbon-based layer (MPL). The fibrous backing material governs the mechanical properties of the GDL (behavior upon compression, bending and shear strength, etc.) while the MPL ensures intimate contact to the catalyst layers, protects the delicate proton exchange membrane against perforation and plays an active role with respect to the water management in the cell during operation. There is consensus that this heterogeneous porosity brought about by this structure (hydrophilic/hydrophobic and various pore sizes) is advantageous for the performance.

Sketch of the bilayer structure of Gas Diffusion Layers


Hydrophobic properties in the backing and the MPL are maintained by adding defined amounts of polytetrafluoroethylene (PTFE) to both sublayers. Various types of carbon particles (carbon blacks, graphite) can be used in the MPL in order to produce different levels of hydrophobicity. Furthermore, the MPL can be used as substrate to deposit catalyst particles for the manufacture of gas diffusion electrodes (GDEs).

SGL Carbon has been producing fully-treated SIGRACET gas diffusion layers by reel-to-reel processes since 1999. Carbon paper-type (prepared by wet-laying of chopped PAN-based carbon fibers) gas diffusion layers are the preferred solution since they can be manufactured at high volumes (scalability) and low thickness. The following figures show the whole value chain of GDL manufacturing. All commercially available GDL materials to date are based on carbon fibers derived from polyacrylonitrile (PAN). PAN (co)polymers are processed into precursor fibers by wet-spinning. Subsequent stabilization and pyrolysis yields high tensile (HT) carbon fibers which are sized and chopped to enable suitable processing by means of papermaking technologies.


Carbon Fiber Production

SGL Carbon's carbon fiber production process

Manufacturing of SIGRAFIL chopped carbon fibers


A primary carbon fiber web is laid by a papermaking technology and subsequent thermobonding. Thereafter, the obtained raw paper is impregnated with carbonisable thermoset resins (with optional addition of carbon fillers), cured and re-carbonized/graphitized. This serves to enhance the mechanical stability and conductivity as well as to adjust the desired porosity level.


Carbon Paper Substrate

Carbon fiber substratum SGL Carbon

Manufacturing route of SIGRACET (carbon paper-based) gas diffusion layer backings


Finishing of GDL comprises hydrophobic treatment of the substrate with PTFE and coating with a microporous layer (MPL).


Finishing Treatment

Finishing treatment of SGL Carbon's carbon fiber paper for fuel cell applications

Finishing treatments of SIGRACET (carbon paper-based) gas diffusion layers


A loading of the substrate with 5% (w/w) PTFE has proven to be sufficient for obtaining a pronounced hydrophobicity. MPLs typically contain 20 to 25% PTFE. This MPL composition has been identified as the optimum ratio for PEMFC performance across a broad range of operating conditions. Mean pore diameters of SIGRACET GDLs are typically in a range from 0.1 to 0.3 μm (Hg-Porosimetry) or 1.5 to 3 μm (calculated from capillary flow porometry). The hydrophobic treatment produces water repellent properties for the substrate and for the MPL (water contact angles by sessile drop method > 130°).

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Sigracet 22 BB

Product Code

Description

Retail Price (USD$)Lead Time & Availability
212202

Sigracet 22 BB

$9 (3*3cm,Item#:212202-0303)

$15 (5*5cm,Item#:212202-0505)

$25 (10*10cm,Item#:212202-1010)

$69 (20*20cm,Item#:212202-2020)

$175 (20*20cm*4pcs,Item#:212202-20204)

$175 (40*40cm,Item#:212202-4040)

1 day & In Stock
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Partial references citing our materials (from Google Scholar)


Carbon Dioxide Reduction

1. ACS Nano Strain Relaxation in Metal Alloy Catalysts Steers the Product Selectivity of Electrocatalytic CO2 Reduction

The bipolar membrane (Fumasep FBM) in this paper was purchased from SCI Materials Hub, which was used in rechargeable Zn-CO2 battery tests. The authors reported a strain relaxation strategy to determine lattice strains in bimetal MNi alloys (M = Pd, Ag, and Au) and realized an outstanding CO2-to-CO Faradaic efficiency of 96.6% with outstanding activity and durability toward a Zn-CO2 battery.


2. Front. Chem. Boosting Electrochemical Carbon Dioxide Reduction on Atomically Dispersed Nickel Catalyst

In this paper, Vulcan XC-72R was purchased from SCI Materials Hub. Vulcan XC 72R carbon is the most common catalyst support used in the anode and cathode electrodes of Polymer Electrolyte Membrane Fuel Cells (PEMFC), Direct Methanol Fuel Cells (DMFC), Alkaline Fuel Cells (AFC), Microbial Fuel Cells (MFC), Phosphoric Acid Fuel Cells (PAFC), and many more!


3. Adv. Mater. Partially Nitrided Ni Nanoclusters Achieve Energy-Efficient Electrocatalytic CO2 Reduction to CO at Ultralow Overpotential

An AEM membrane (Sustainion X37-50 Grade RT, purchased from SCI Materials Hub) was activated in 1 M KOH for 24 h, washed with ultra-purity water prior to use.


4. Adv. Funct. Mater. Nanoconfined Molecular Catalysts in Integrated Gas Diffusion Electrodes for High-Current-Density CO2 Electroreduction

In this paper (Supporting Information), an anion exchanged membrane (Fumasep FAB-PK-130 obtained from SCI Materials Hub (www.scimaterials.cn)) was used to separate the catholyte and anolyte chambers.

SCI Materials Hub: we also recommend our Fumasep FAB-PK-75 for the use in a flow cell.


5. Appl. Catal. B Efficient utilization of nickel single atoms for CO2 electroreduction by constructing 3D interconnected nitrogen-doped carbon tube network

In this paper, the Nafion 117 membrane was obtained from SCI Materials Hub.


6. Vacuum Modulable Cu(0)/Cu(I)/Cu(II) sites of Cu/C catalysts derived from MOF for highly selective CO2 electroreduction to hydrocarbons

In this paper, Proton exchange membrane (Nafion 117), Nafion D520, and Toray 060 carbon paper were purchased from SCI Materials Hub.


7. National Science Review Confinement of ionomer for electrocatalytic CO2 reduction reaction via efficient mass transfer pathways

An anion exchange membrane (PiperION-A15-HCO3) was obtained from SCI Materials Hub.


8. Catalysis Communications Facilitating CO2 electroreduction to C2H4 through facile regulating {100} & {111} grain boundary of Cu2O

Carbon paper (TGPH060), membrane solution (Nafion D520), and ionic membrane (Nafion N117) were obtained from Wuhu Eryi Material Technology Co., Ltd (a company under SCI Materials Hub).


Batteries

1. J. Mater. Chem. A Blocking polysulfides with a Janus Fe3C/N-CNF@RGO electrode via physiochemical confinement and catalytic conversion for high-performance lithium–sulfur batteries

Graphene oxide (GO) in this paper was obtained from SCI Materials Hub. The authors introduced a Janus Fe3C/N-CNF@RGO electrode consisting of 1D Fe3C decorated N-doped carbon nanofibers (Fe3C/N-CNFs) side and 2D reduced graphene oxide (RGO) side as the free-standing carrier of Li2S6 catholyte to improve the overall electrochemical performance of Li-S batteries.


2. Joule A high-voltage and stable zinc-air battery enabled by dual-hydrophobic-induced proton shuttle shielding

This paper used more than 10 kinds of materials from SCI Materials Hub and the authors gave detailed properity comparsion.

The commercial IEMs of Fumasep FAB-PK-130 and Nafion N117 were obtained from SCI Materials Hub.

Gas diffusion layers of GDL340 (CeTech) and SGL39BC (Sigracet) and Nafion dispersion (Nafion D520) were obtained from SCI Materials Hub.

Zn foil (100 mm thickness) and Zn powder were obtained from the SCI Materials Hub.

Commercial 20% Pt/C, 40% Pt/C and IrO2 catalysts were also obtained from SCI Materials Hub.


3. Journal of Energy Chemistry Vanadium oxide nanospheres encapsulated in N-doped carbon nanofibers with morphology and defect dual-engineering toward advanced aqueous zinc-ion batteries

In this paper, carbon cloth (W0S1011) was obtained from SCI Materials Hub. The flexible carbon cloth matrix guaranteed the stabilization of the electrode and improved the conductivity of the cathode.


4. Energy Storage Materials Defect-abundant commercializable 3D carbon papers for fabricating composite Li anode with high loading and long life

The 3D carbon paper (TGPH060 raw paper) were purchased from SCI Materials Hub.


5. Nanomaterials A Stable Rechargeable Aqueous Zn–Air Battery Enabled by Heterogeneous MoS2 Cathode Catalysts

Nafion D520 (5 wt%), and carbon paper (GDL340) were received from SCI-Materials-Hub.


6. SSRN An Axially Directed Cobalt-Phthalocyanine Covalent Organic Polymer as High-Efficient Bifunctional Catalyst for Zn-Air Battery

Carbon cloth (W0S1011) and other electrochemical consumables required for air cathode were provided by SCI Materials Hub.


Oxygen Reduction Reaction

1. J. Chem. Eng. Superior Efficiency Hydrogen Peroxide Production in Acidic Media through Epoxy Group Adjacent to Co-O/C Active Centers on Carbon Black

In this paper, Vulcan XC 72 carbon black, ion membrane (Nafion N115, 127 μL), Nafion solution (D520, 5 wt%), and carbon paper (AvCarb GDS 2230 and Spectracarb 2050A-1050) were purchased from SCI Materials Hub.


2. Journal of Colloid and Interface Science Gaining insight into the impact of electronic property and interface electrostatic field on ORR kinetics in alloy engineering via theoretical prognostication and experimental validation

The 20 wt% Pt3M (M = Cr, Co, Cu, Pd, Sn, and Ir) were purchased from SCI Materials Hub. This work places emphasis on the kinetics of the ORR concerning Pt3M (M = Cr, Co, Cu, Pd, Sn, and Ir) catalysts, and integrates theoretical prognostication and experimental validation to illuminate the fundamental principles of alloy engineering.


Water Electrolysis

1. International Journal of Hydrogen Energy Gold as an efficient hydrogen isotope separation catalyst in proton exchange membrane water electrolysis

The cathodic catalysts of Pt/C (20 wt%, 2–3 nm) and Au/C (20 wt%, 4–5 nm) were purchased from SCI Materials Hub.


2. Small Science Silver Compositing Boosts Water Electrolysis Activity and Durability of RuO2 in a Proton-Exchange-Membrane Water Electrolyzer

Two fiber felts (0.35 mm thickness, SCI Materials Hub) were used as the porous transport layers at both the cathode and the anode.


3. Advanced Functional Materials Hierarchical Crystalline/Amorphous Heterostructure MoNi/NiMoOx for Electrochemical Hydrogen Evolution with Industry-Level Activity and Stability

Anion-exchange membrane (FAA-3-PK-130) was obtained from SCI Materials Hub website.


Fuel Cells

1. Polymer Sub-two-micron ultrathin proton exchange membrane with reinforced mechanical strength

Gas diffusion electrode (60% Pt/C, Carbon paper) was purchased from SCI Materials Hub.


Characterization

1. Chemical Engineering Journal Electrochemical reconstitution of Prussian blue analogue for coupling furfural electro-oxidation with photo-assisted hydrogen evolution reaction

An Au nanoparticle film was deposited on the total reflecting plane of a single reflection ATR crystal (SCI Materials Hub, Wuhu, China) via sputter coater.

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