⚡ The Dual Champions of High-Performance PVDF Binder Systems — Arkema Kynar® HSV900 and KYNAR FLEX® 2801-00
In high-energy-density lithium-ion batteries, the binder plays a crucial role in determining electrode conductivity, structural stability, and cycling life. Among the top-performing PVDF binder systems available today, Arkema’s Kynar® HSV900 and KYNAR FLEX® 2801-00 stand out as the two benchmark materials—representing the dual directions of rigid structural stability and flexible copolymer modification.
Kynar® HSV900 is a high-purity polyvinylidene fluoride (PVDF) powder binder developed by Arkema specifically for high-nickel cathodes and silicon–carbon anodes. It offers excellent solubility, adhesion, and electrochemical stability, making it ideal for advanced electrode fabrication.
🌟 Key Features
💡 High adhesion with low loading: Strong electrode bonding allows for reduced binder content.
🔥 Fast dissolving and easy processing: Quickly dissolves in NMP, suitable for high-speed coating lines.
⚡ Low impedance, high stability: Minimal impedance growth during cycling; compatible with high-voltage systems.
🌡 Superior thermal and chemical stability: Maintains performance under harsh, high-temperature, and high-voltage conditions.
💎 2. KYNAR FLEX® 2801-00 – PVDF-HFP Copolymer for Flexibility and Chemical Resistance
KYNAR FLEX® 2801-00 is a copolymer of PVDF and hexafluoropropylene (HFP), combining excellent flexibility, corrosion resistance, and thermal stability. It is widely used in electrode binders, separator coatings, and functional polymer films, and also serves as a polyolefin processing aid (PPA).
🌟 Product Highlights
🔸 High flexibility: Elongation at break >50%, retains ductility even at low temperature.
🔸 Strong chemical resistance: Stable under strong acid, alkali, and extreme pH environments.
🔸 High decomposition temperature: Up to 410 °C in N₂ atmosphere.
🔸 Excellent insulation: Stable dielectric constant, surface resistivity up to 10¹¹ Ω.
🔸 Outstanding flame resistance: LOI 42%, UL V-0 fire rating.
⚙️ 3. Technical Comparison Table
Category
Test Parameter
Unit
Kynar® HSV900
KYNAR FLEX® 2801-00
Test Standard
General Info
Type
—
PVDF Homopolymer
PVDF-HFP Copolymer
—
Physical Properties
Density
g/cm³
1.77–1.79
1.77–1.80
ISO 1183
Average Particle Size D₅₀
μm
10
10
GB/T 19077
Moisture Absorption
%
<0.1
0.03
GB/T 6283 / ISO 62
Thermal Properties
Melting Point
°C
165
143
ASTM D3418 / ISO 11357
Decomposition Temp (N₂)
°C
390
410
TGA
Oxygen Index (LOI)
%
44
42
ASTM D2863
Mechanical Properties
Tensile Strength
MPa
—
20–34.5
ASTM D638
Elongation at Break
%
—
>50
ISO 527
Electrical Properties
Dielectric Constant (1 MHz)
—
—
7
IEC 60250
Surface Resistivity
Ω
—
≥5.1×10¹¹
ASTM D257
Processing Properties
Melt Viscosity (230 °C, 100 s⁻¹)
kPo
50
—
ASTM D3835
Solution Viscosity (5% PVDF, 10 s⁻¹)
cPo
510
—
—
Compatibility
Compatible Systems
—
NCM/NCA, LFP, Si–C
PVDF, LLDPE, EVA blends
—
🧪 4. Application Recommendations
Application Area
HSV900
2801-00
High-Ni Cathodes
✅
✅
LFP Cathodes
✅
✅
Graphite Anodes
✅
✅
Si–C Anodes
✅
✅
Separator Coatings
—
✅
High-Voltage Systems
✅
✅
🧩 5. Packaging and Ordering Information
Specification
Packaging Type
Description
1 g / 10 g / 50 g / 100 g / 200 g / 500 g / 1 kg
Bottle or Pouch
Suitable for lab and pilot testing
20 kg Industrial Pack
Original Paper Bag
Ideal for production and scale-up
Documents Provided: TDS / COA / MSDS Product Form: White powder Availability: Regular stock Invoice: 13% VAT invoice available
Support: Technical consultation, material selection, and formulation optimization
✨ Conclusion
Kynar® HSV900 provides robust adhesion and electrochemical stability, making it the binder of choice for high-energy cathode and anode formulations. KYNAR FLEX® 2801-00, with its superior flexibility and chemical resistance, excels in composite coatings and next-generation battery systems.
When used together, they create an ideal balance between mechanical strength, interface stability, and cycling durability, supporting the evolution of the next generation of high-energy-density batteries.
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